التفاصيل البيبلوغرافية
| العنوان: |
Process for the preparation of ethylene copolymer |
| Patent Number: |
4,721,761 |
| تاريخ النشر: |
January 26, 1988 |
| Appl. No: |
06/892,030 |
| Application Filed: |
July 28, 1986 |
| مستخلص: |
The present invention relates to an improved process for the preparation of an ethylene copolymer. In the copolymerization of a comonomer copolymerizable with ethylene and ethylene at a pressure of 500 to 3,000 kg/cm.sup.2 and at a temperature of 100.degree. to 350.degree. C. using an initiator in the presence or absence of a chain transfer agent, a gap between a packing and a retainer of an ultrahigh pressure pump for copolymerization is filled with a grease containing a polymerization inhibitor. The comonomer and a part or the whole of ethylene are mixed under an elevated pressure and then introduced into a reaction vessel. In accordance with the present invention, leakage of the comonomer from the packing of the pump, clogging of a conduit and breakage of the pump can be prevented, thus improving operation efficiency. Furthermore, the effect of diffusion of the comonomer into ethylene gas is attained sufficiently, thus enabling the production of a high-quality polymer having less gel content. This facilitates the reaction control, improving the reaction stability. |
| Inventors: |
Omae, Tadayuki (Chiba, JPX); Yamaguchi, Noboru (Chiba, JPX); Kondo, Akira (Chiba, JPX); Okada, Takayuki (Chiba, JPX) |
| Assignees: |
Sumitomo Chemical Company, Limited (Osaka, JPX) |
| Claim: |
What is claimed is |
| Claim: |
1. A process for the preparation of an ethylene copolymer which comprises introducing ethylene and one or more comonomers having a Q value (copolymerization reactivity index) of 0.1 or more, which are copolymerizable with ethylene, into a tank-shaped or tubular reaction vessel by means of an ultrahigh pressure pump and copolymerizing the comonomer or comonomers with ethylene at a pressure of 500 to 3,000 kg/cm.sup.2 and at a temperature of 100.degree. to 350.degree. C. using an initiator in the presence or absence of a chain transfer agent, characterized in that (1) a gap between a packing and a retainer in the ultrahigh pressure pump for the comonomer is filled with a grease having incorporated thereinto 2 to 20% by weight of a polymerization inhibitor, and that (2) the comonomer or comonomers and a part or the whole of ethylene which has been compressed by a compressor are previously mixed with each other at the point where heat transfer from the reaction vessel is negligible before being introduced into the reaction vessel. |
| Claim: |
2. A process as claimed in claim 1, wherein said comonomer is selected from the group consisting of acrylic acid, methacrylic acid, ethyl acrylate, ethyl methacrylate, methyl acrylate, methyl methacrylate, glycidyl acrylate, glycidyl methacrylate, dimethylaminoethyl methacrylate, and maleic anhydride. |
| Claim: |
3. A process for the preparation of an ethylene copolymer which comprises introducing ethylene and one or more comonomers having a Q value (copolymerization reactivity index) of 0.1 or more which are copolymerizable with ethylene into a tank-shaped or tubular reaction vessel by means of an ultrahigh pressure pump, and copolymerizing the comonomer or comonomers with ethylene at a pressure of 500 to 3,000 kg/cm.sup.2 and at a temperature of 100.degree. to 350.degree. C. using an initiator in the presence or absence of a chain transfer agent, characterized in that (1) a gap between a packing and a retainer of the ultrahigh pressure pump for the comonomer is filled with a grease having incorporated thereinto 2 to 20% by weight of a polymerization inhibitor and 100 to 5,000 ppm by weight of a polymerization inhibitor is added to a lubricating oil in the ultrahigh pressure pump for the comonomer and that (2) the comonomer or comonomers and a part or the whole of ethylene which has been compressed by a compressor are previously mixed with each other at the point where heat transfer form the reaction vessel is negligible before being introduced into the reaction vessel. |
| Claim: |
4. A process as claimed in claim 1, wherein said comonomer is selected from the group consisting of acrylic acid, methacrylic acid, ethyl acrylate, ethyl methacrylate, methyl acrylate, methyl methacrylate, glycidyl acrylate, glycidyl methacrylate, dimethylaminoethyl methacrylate, and maleic anhydride. |
| Current U.S. Class: |
526/64; 526/272; 526/273; 5263/186; 526/320; 526/329 |
| Current International Class: |
C08F 242; C08F21002 |
| Primary Examiner: |
Schofer, Joseph L. |
| Assistant Examiner: |
Teskin, F. M. |
| Attorney, Agent or Firm: |
Sughrue, Mion, Zinn, Macpeak and Seas |
| رقم الانضمام: |
edspgr.04721761 |
| قاعدة البيانات: |
USPTO Patent Grants |