Electronic Resource
N-(diisopropylphosphanyl)Benzamide
| العنوان: | N-(diisopropylphosphanyl)Benzamide |
|---|---|
| المؤلفون: | Universidad de Sevilla. Departamento de Química Inorgánica, Ministerio de Ciencia e Innovación (MICIN). España, Junta de Andalucía, Alcaide, María M., García Garrido, D., Álvarez, E., Peloso, Riccardo |
| بيانات النشر: | Multidisciplinary Digital Publishing Institute (MDPI) 2023 |
| نوع الوثيقة: | Electronic Resource |
| مستخلص: | N-(diisopropylphosphanyl)benzamide, PhC(O)NHPiPr2, has been synthesized in good yield following two alternative procedures that employ benzamide as the starting material. The first one is a two-step preparation, in which N-(trimetilsilyl)benzamide is reacted with PiPr2Cl to give the title compound in good yield, whereas the second one is a straightforward synthesis which converts benzamide into N-(diisopropylphosphanyl)benzamide by reaction with PiPr2Cl in the presence of N,N-dimethylpyridin-4-amine (DMAP) and triethylamine. NMR spectroscopy and X-ray diffraction analyses have been performed to characterize the new compound and elucidate its molecular structure in the solid state. N-(diisopropylphosphanyl)benzamide adds to the limited family of amido-substituted phosphines, RC(O)NHPR’2, which can be classified as bidentate hybrid P,O-ligands, both in their neutral and anionic forms, the latter achievable by deprotonation of the NH group. |
| مصطلحات الفهرس: | Hemilabile ligands, P ligands, P(III) compounds, Sterically demanding ligands, info:eu-repo/semantics/article |
| URL: | MolBank, 2023 (2), M1667. CTQ2017–82893-C2–2-R CTQ2016–75193-P PID2019–110856GA-I00 US126226 P18-FR-4688 |
| الاتاحة: | Open access content. Open access content http://creativecommons.org/licenses/by/4.0 info:eu-repo/semantics/openAccess Atribución 4.0 Internacional |
| ملاحظة: | English |
| Other Numbers: | SUE oai:idus.us.es:11441/158022 Alcaide, M.M., García Garrido, D., Álvarez, E. y Peloso, R. (2023). N-(diisopropylphosphanyl)Benzamide. MolBank, 2023 (2), M1667. https://doi.org/10.3390/M1667. 1422-8599 10.3390/M1667 1442719977 |
| المصدر المساهم: | UNIV DE SEVILLA From OAIster®, provided by the OCLC Cooperative. |
| رقم الانضمام: | edsoai.on1442719977 |
| قاعدة البيانات: | OAIster |
| الوصف غير متاح. |