Electronic Resource
Diastereodivergent Synthesis of 2‑Ene-1,4-hydroxy Sulfides from 2‑Sulfinyl Dienes via Tandem Sulfa-Michael/Sulfoxide-Sulfenate Rearrangement
| العنوان: | Diastereodivergent Synthesis of 2‑Ene-1,4-hydroxy Sulfides from 2‑Sulfinyl Dienes via Tandem Sulfa-Michael/Sulfoxide-Sulfenate Rearrangement |
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| المؤلفون: | Ministerio de Economía y Competitividad (España), Fernández de la Pradilla, Roberto [0000-0002-6633-8499], Viso, Alma [0000-0003- 2622-4777], Velado, Marina, Fernández de la Pradilla, Roberto, Viso, Alma |
| بيانات النشر: | American Chemical Society 2021 |
| نوع الوثيقة: | Electronic Resource |
| مستخلص: | The highly diastereoselective sulfa-Michael addition of thiolates to enantiopure 2-sulfinyl dienes leads to anti or syn 2- ene-1,4-hydroxy sulfides in good yields and selectivities dependent on the reaction conditions in a diastereodivergent process. Synthetic applications of these enantiopure hydroxy sulfides by subsequent sigmatropic rearrangements have been outlined. |
| مصطلحات الفهرس: | artículo |
| URL: | Postprint Sí info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/CTQ2016-77555-C2-2-R info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2019-107380GB-100 |
| الاتاحة: | Open access content. Open access content openAccess |
| ملاحظة: | English |
| Other Numbers: | CTK oai:digital.csic.es:10261/232257 Organic Letters 23 : 202−206 (2021) 1523-7060 10.1021/acs.orglett.0c03929 1523-7052 1286565061 |
| المصدر المساهم: | CSIC From OAIster®, provided by the OCLC Cooperative. |
| رقم الانضمام: | edsoai.on1286565061 |
| قاعدة البيانات: | OAIster |
| الوصف غير متاح. |