Electronic Resource
Multifunctional, Defect-Engineered Metal-Organic Frameworks with Ruthenium Centers: Sorption and Catalytic Properties
| العنوان: | Multifunctional, Defect-Engineered Metal-Organic Frameworks with Ruthenium Centers: Sorption and Catalytic Properties |
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| المؤلفون: | Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química, Ministerio de Ciencia e Innovación, Kozachuk, O., Luz Mínguez, Ignacio, Llabrés i Xamena, Francesc Xavier, Noei, H., Kauer, M., Albada, H.B., Bloch, E.D., Marler, B., Wang, Y.M., Muhler, M., Fischer, R.A. |
| بيانات النشر: | Wiley Hispana 2014-07 |
| نوع الوثيقة: | Electronic Resource |
| مستخلص: | A mixed-linker solid-solution approach was employed to modify the metal sites and introduce structural defects into the mixed-valence Ru-II/III structural analogue of the well-known MOF family [M-3(II,II)(btc)(2)] (M= Cu, Mo, Cr, Ni, Zn; btc= benzene-1,3,5-tricarboxylate), with partly missing carboxylate ligators at the Ru-2 paddle-wheels. Incorporation of pyridine-3,5-dicarboxylate (pydc), which is the same size as btc but carries lower charge, as a second, defective linker has led to the mixed-linker isoreticular derivatives of Ru-MOF, which display characteristics unlike those of the defect-free framework. Along with the creation of additional coordinatively unsaturated sites, the incorporation of pydc induces the partial reduction of ruthenium. Accordingly, the modified Ru sites are responsible for the activity of the "defective" variants in the dissociative chemisorption of CO2, the enhanced performance in CO sorption, the formation of hydride species, and the catalytic hydrogenation of olefins. |
| مصطلحات الفهرس: | CO2 reduction, Heterogeneous Catalysis, Hydrogen splitting, Metal-Organic Frameworks, Structural defects, info:eu-repo/semantics/article |
| URL: | "Severo Ochoa" program |
| الاتاحة: | Open access content. Open access content http://rightsstatements.org/vocab/InC/1.0 info:eu-repo/semantics/openAccess |
| ملاحظة: | TEXT English |
| Other Numbers: | UPV oai:riunet.upv.es:10251/63867 urn:issn:1433-7851 info:doi:10.1002/anie.201311128 https://riunet.upv.es/bitstream/10251/63867/14/angew RuMOFs.pdf.jpg 1138432423 |
| المصدر المساهم: | UNIVERSITAT POLITECNICA DE VALENCIA From OAIster®, provided by the OCLC Cooperative. |
| رقم الانضمام: | edsoai.on1138432423 |
| قاعدة البيانات: | OAIster |
| الوصف غير متاح. |