Electronic Resource
Self-Assembled Monolayers of Alkanethiols on Gold: Monolayers Derived From Two Components with Alkane Chains of Different Lengths
| العنوان: | Self-Assembled Monolayers of Alkanethiols on Gold: Monolayers Derived From Two Components with Alkane Chains of Different Lengths |
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| المؤلفون: | HARVARD UNIV CAMBRIDGE MA DEPT OF CHEMISTRY, Folkers, J. P., Laibinis, P. E., Whitesides, G. M. |
| المصدر: | DTIC AND NTIS |
| بيانات النشر: | 1992-07 |
| نوع الوثيقة: | Electronic Resource |
| مستخلص: | This paper describes the preparation and wetting properties of two-component self-assembled monolayers (SAMs) obtained by the competitive adsorption of one short-chain (HS(CH2)1OSh) and one long-chain (HS(CH2)21LG) alkanethiol onto gold from dilute ethanolic solutions. The four possible combinations of the tail groups CH3 and CH20H were investigated: Sh = CH3/Lg = CH20H, Sh = CH2OH/Lg = CH3, SH = CH2OH/Lg = CH2OH, and Sh = CH3/Lg = CH3. The compositions of these SAMs are not the same as the compositions of the solutions from which they were formed, and the relationship between these compositions suggests that the SAMs have partially phase separated. Contact angles with water and hexadecane, however, show that significant disorder still remains in the interfacial region. |
| مصطلحات الفهرس: | Organic Chemistry, Physical Chemistry, ALKANES, WETTING, GOLD, CHAINS, PREPARATION, LENGTH, ADSORPTION, SELF-ASSEMBLED MONOLAYERS, ALKANETHIOLS, ETHANOLIC SOLUTIONS, MOLECULAR DYNAMICS CALCULATIONS, ORGANIC INTERFACES, TAIL GROUPS., Text |
| URL: | |
| الاتاحة: | Open access content. Open access content Approved for public release; distribution is unlimited. |
| ملاحظة: | text/html English |
| Other Numbers: | DTICE ADA254901 832018300 |
| المصدر المساهم: | From OAIster®, provided by the OCLC Cooperative. |
| رقم الانضمام: | edsoai.ocn832018300 |
| قاعدة البيانات: | OAIster |
| الوصف غير متاح. |