Academic Journal
Diastereo-selective synthesis of CF3-substituted epoxide via in situ generated trifluoroethylideneiodonium ylide
| العنوان: | Diastereo-selective synthesis of CF3-substituted epoxide via in situ generated trifluoroethylideneiodonium ylide |
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| المؤلفون: | Chenxin Ge, Chao Chen |
| المصدر: | Green Synthesis and Catalysis, Vol 4, Iss 4, Pp 334-337 (2023) |
| بيانات النشر: | KeAi Communications Co. Ltd., 2023. |
| سنة النشر: | 2023 |
| المجموعة: | LCC:Chemical technology LCC:Biochemistry |
| مصطلحات موضوعية: | Trifluoromethyl, Epoxidation, Epoxides, Iodonium ylide, Trifluoroethylidenation, Chemical technology, TP1-1185, Biochemistry, QD415-436 |
| الوصف: | The first example for the generation of 2,2,2-trifluoroethylidene ylide from corresponding iodonium salt is reported, which has been successfully applied in the epoxidation of aldehydes, achieving the corresponding trifluoromethylated epoxides in high yields and diastereo-selectivities. |
| نوع الوثيقة: | article |
| وصف الملف: | electronic resource |
| اللغة: | English |
| تدمد: | 2666-5549 |
| Relation: | http://www.sciencedirect.com/science/article/pii/S2666554922000771; https://doaj.org/toc/2666-5549 |
| DOI: | 10.1016/j.gresc.2022.07.005 |
| URL الوصول: | https://doaj.org/article/ef692e79bfcd4784b94e9070022229a5 |
| رقم الانضمام: | edsdoj.f692e79bfcd4784b94e9070022229a5 |
| قاعدة البيانات: | Directory of Open Access Journals |
Full Text Finder | تدمد: | 26665549 |
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| DOI: | 10.1016/j.gresc.2022.07.005 |