التفاصيل البيبلوغرافية
| العنوان: |
New Iron(II) Spin Crossover Complexes with Unique Supramolecular Networks Assembled by Hydrogen Bonding and Intermetallic Bonding |
| المؤلفون: |
Takashi Kosone, Itaru Tomori, Daisuke Akahoshi, Toshiaki Saito, Takafumi Kitazawa |
| المصدر: |
Crystals, Vol 8, Iss 11, p 415 (2018) |
| بيانات النشر: |
MDPI AG, 2018. |
| سنة النشر: |
2018 |
| المجموعة: |
LCC:Crystallography |
| مصطلحات موضوعية: |
coordination polymer, supramolecular isomerism, spin crossover, crystal engineering, Crystallography, QD901-999 |
| الوصف: |
Two spin crossover (SCO) coordination polymers assembled by combining FeII octahedral ion, 4-cyanopyridine (4-CNpy) and [Au(CN)2]− liner unit are described. These compounds, Fe(4-CNpy)2[Au(CN)2]2·1/2(4-CNpy) (1a) and {Fe(4-CNpy)2[Au(CN)2]2}-{Fe(H2O)2[Au(CN)2]2} (1b), present quite different supramolecular networks that show different magnetic behaviors. Compound 1a crystallizes in the centrosymmetric space group Pbcn. The asymmetric unit contains two 4-CNpy, one type of Fe2+, and two types of crystallographically distinct [Au(CN)2]− units which form Hofmann-like two dimensional layer structures with guest spaces. The layers are combined with another layer by strong gold-gold intermetalic interactions. Compound 1b crystallizes in the centrosymmetric space group Pnma. The bent bismonodentate [AuI(CN)2] units and FeII ions form a complicated interpenetrated three dimensional structure. In addition, 1b exhibits ferromagnetic interaction. |
| نوع الوثيقة: |
article |
| وصف الملف: |
electronic resource |
| اللغة: |
English |
| تدمد: |
2073-4352 |
| Relation: |
https://www.mdpi.com/2073-4352/8/11/415; https://doaj.org/toc/2073-4352 |
| DOI: |
10.3390/cryst8110415 |
| URL الوصول: |
https://doaj.org/article/be3ef9e60ac545848889e698e51299d9 |
| رقم الانضمام: |
edsdoj.be3ef9e60ac545848889e698e51299d9 |
| قاعدة البيانات: |
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