Academic Journal

A Novel Synthesis Method of Dumbbell-like (Gd1−xTbx)2O(CO3)2·H2O Phosphor for Latent Fingerprint

التفاصيل البيبلوغرافية
العنوان: A Novel Synthesis Method of Dumbbell-like (Gd1−xTbx)2O(CO3)2·H2O Phosphor for Latent Fingerprint
المؤلفون: Lei Huang, Jian Qian, Shijian Sun, Zheng Li, Dechuan Li
المصدر: Molecules, Vol 29, Iss 16, p 3846 (2024)
بيانات النشر: MDPI AG, 2024.
سنة النشر: 2024
المجموعة: LCC:Organic chemistry
مصطلحات موضوعية: Gd3+, Tb3+, fingerprint, phosphor, Organic chemistry, QD241-441
الوصف: A novel method for synthesizing dumbbell-shaped (Gd1−xTbx)2O(CO3)2·H2O (GOC:xTb3+) phosphors using sodium carbonate was investigated. An amount of 1 mmol of stable fluorescent powder can be widely prepared using 3–11 mmol of Na2CO3 at a pH value of 8.5–10.5 in the reaction solution. The optimal reaction conditions for the phosphors were determined to be 7 mmol for the amount of sodium carbonate and a pH of 9.5 in the solution. Mapping analysis of the elements confirmed uniform distribution of Gd3+ and Tb3+ elements in GOC:xTb3+. The analysis of fluorescence intensity shows that an optimal excitation wavelength of 273 nm is observed when the concentration of Tb3+ is between 0.005 and 0.3. The highest emission intensity was observed for GOC:0.05Tb3+ with a 57.5% maximum quantum efficiency. The chromaticity coordinates show that the color of GOC:Tb3+ is stable and suitable for fluorescence recognition. Latent fingerprint visualization reveals distinctive features like whorls, hooks, and bifurcations. Therefore, the sodium carbonate method offers an effective alternative to traditional urea chemical reaction conditions for preparing GOC:Tb3+.
نوع الوثيقة: article
وصف الملف: electronic resource
اللغة: English
تدمد: 29163846
1420-3049
Relation: https://www.mdpi.com/1420-3049/29/16/3846; https://doaj.org/toc/1420-3049
DOI: 10.3390/molecules29163846
URL الوصول: https://doaj.org/article/bc671ffa57714c4783641dfb7e922beb
رقم الانضمام: edsdoj.bc671ffa57714c4783641dfb7e922beb
قاعدة البيانات: Directory of Open Access Journals
الوصف
تدمد:29163846
14203049
DOI:10.3390/molecules29163846