Academic Journal
Sustainable Extraction Methods Affect Metabolomics and Oxidative Stability of Myrtle Seed Oils Obtained from Myrtle Liqueur By-Products: An Electron Paramagnetic Resonance and Mass Spectrometry Approach
| العنوان: | Sustainable Extraction Methods Affect Metabolomics and Oxidative Stability of Myrtle Seed Oils Obtained from Myrtle Liqueur By-Products: An Electron Paramagnetic Resonance and Mass Spectrometry Approach |
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| المؤلفون: | Angela Fadda, Paola Montoro, Gilda D’Urso, Nicoletta Ravasio, Federica Zaccheria, Daniele Sanna |
| المصدر: | Antioxidants, Vol 12, Iss 1, p 154 (2023) |
| بيانات النشر: | MDPI AG, 2023. |
| سنة النشر: | 2023 |
| المجموعة: | LCC:Therapeutics. Pharmacology |
| مصطلحات موضوعية: | green chemistry, metabolomics, LC-MS, electron paramagnetic resonance spectroscopy, food waste, multivariate data analysis, Therapeutics. Pharmacology, RM1-950 |
| الوصف: | Myrtle liqueur production generates high amounts of by-products that can be employed for the extraction of bioactive compounds. Bio-based, non-toxic and biodegradable solvents (ethyl acetate and 2-methyltetrahydrofuran), and a mechanical extraction were applied to myrtle seeds, by-products of the liqueur production, to extract oils rich in phenolic compounds. The oils obtained were characterized for yield, peroxide value (PV), lipid composition, and total phenolic concentration (TPC). The phenolic profile of the oils, determined by LC-MS, the antioxidant activity, and the oxidative stability were also analyzed. A validated UHPLC-ESI-QTRAP-MS/MS analytical method in multiple reaction monitoring (MRM) mode was applied to quantify myricetin and its main derivatives in myrtle oils. The results pointed out clear differences among extraction methods on myricetin concentration. The oxidative stability of myrtle oils was studied with electron paramagnetic resonance (EPR) spectroscopy highlighting the effect of the extraction method on the oxidation status of the oils and the role of phenolic compounds in the evolution of radical species over time. A principal component analysis applied to LC-MS data highlighted strong differences among phenolic profiles of the oils and highlighted the role of myricetin in the oxidative stability of myrtle oils. Myrtle oil, obtained from the by-products of myrtle liqueur processing industry, extracted with sustainable and green methods might have potential application in food or cosmetic industries. |
| نوع الوثيقة: | article |
| وصف الملف: | electronic resource |
| اللغة: | English |
| تدمد: | 12010154 2076-3921 |
| Relation: | https://www.mdpi.com/2076-3921/12/1/154; https://doaj.org/toc/2076-3921 |
| DOI: | 10.3390/antiox12010154 |
| URL الوصول: | https://doaj.org/article/b44da703279b46c5b58e28a5f8583b28 |
| رقم الانضمام: | edsdoj.b44da703279b46c5b58e28a5f8583b28 |
| قاعدة البيانات: | Directory of Open Access Journals |
Full Text Finder | تدمد: | 12010154 20763921 |
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| DOI: | 10.3390/antiox12010154 |