التفاصيل البيبلوغرافية
| العنوان: |
Two-dimensional dysprosium(III) coordination polymer: Structure, single-molecule magnetic behavior, proton conduction, and luminescence |
| المؤلفون: |
Jin-Fen Chen, Yi-Liang Ge, Dong-Hui Wu, Hao-Tian Cui, Zhi-Lin Mu, Hong-Ping Xiao, Xinhua Li, Jing-Yuan Ge |
| المصدر: |
Frontiers in Chemistry, Vol 10 (2022) |
| بيانات النشر: |
Frontiers Media S.A., 2022. |
| سنة النشر: |
2022 |
| المجموعة: |
LCC:Chemistry |
| مصطلحات موضوعية: |
coordination polymer, dysprosium, slow magnetic relaxation, proton conduction, multifunctional, Chemistry, QD1-999 |
| الوصف: |
A new dysprosium (III) coordination polymer [Dy(Hm-dobdc) (H2O)2]·H2O (Dy-CP), was hydrothermal synthesized based on 4,6-dioxido-1,3-benzenedicarboxylate (H4m-dobdc) ligand containing carboxyl and phenolic hydroxyl groups. The Dy(III) center adopts an octa-coordinated [DyO8] geometry, which can be described as a twisted square antiprism (D4d symmetry). Neighboring Dy(III) ions are interconnected by deprotonated Hm-dobdc3− ligand to form the two-dimensional infinite layers, which are further linked to generate three-dimensional structure through abundant hydrogen bonds mediated primarily by coordinated and lattice H2O molecules. Magnetic studies demonstrates that Dy-CP shows the field-induced slow relaxation of magnetization and the energy barrier Ueff/kB and relaxation time τ0 are 35.3 K and 1.31 × 10–6 s, respectively. Following the vehicular mechanism, Dy-CP displays proton conductivity with σ equal to 7.77 × 10–8 S cm−1 at 353 K and 30%RH. Moreover, luminescence spectra reveal that H4m-dobdc can sensitize characteristic luminescence of Dy(III) ion. Herein, good magnetism, proton conduction, and luminescence are simultaneously achieved, and thus, Dy-CP is a potential multifunctional coordination polymer material. |
| نوع الوثيقة: |
article |
| وصف الملف: |
electronic resource |
| اللغة: |
English |
| تدمد: |
2296-2646 |
| Relation: |
https://www.frontiersin.org/articles/10.3389/fchem.2022.974914/full; https://doaj.org/toc/2296-2646 |
| DOI: |
10.3389/fchem.2022.974914 |
| URL الوصول: |
https://doaj.org/article/b1ab4d697a0746ada5942fc24d853786 |
| رقم الانضمام: |
edsdoj.b1ab4d697a0746ada5942fc24d853786 |
| قاعدة البيانات: |
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