Academic Journal

Interaction study of molten uranium with multilayer SiC/Y2O3 and Mo/Y2O3 coated graphite

التفاصيل البيبلوغرافية
العنوان: Interaction study of molten uranium with multilayer SiC/Y2O3 and Mo/Y2O3 coated graphite
المؤلفون: S.K. Sharma, M.T. Saify, Sanjib Majumdar, Palash K. Mollick
المصدر: Nuclear Engineering and Technology, Vol 55, Iss 5, Pp 1855-1862 (2023)
بيانات النشر: Elsevier, 2023.
سنة النشر: 2023
المجموعة: LCC:Nuclear engineering. Atomic power
مصطلحات موضوعية: Uranium, Graphite crucible, Vacuum induction melting (VIM), Plasma spray coating, Chemical vapour deposition (CVD), Nuclear engineering. Atomic power, TK9001-9401
الوصف: Graphite crucibles are used for melting uranium and its alloys in VIM furnace. Various coating materials namely Al2O3, ZrO2, MgO etc. are applied on the inner surface of the crucibles using paint brush or thermal spray technique to mitigate U-C interaction. These leads to significant amount of carbon pick-up in uranium. In this study, the attempts are made to develop multilayer coatings comprising of SiC/Y2O3 and Mo/Y2O3 on graphite to study the feasibility of minimizing U-C interaction. The parameters are optimized to prepare SiC coating of about 70μm thickness using CVD technique on graphite coupons and subsequently Y2O3 coating of about 250μm thickness using plasma spray technique. Molybdenum and Y2O3 layers were deposited using plasma spray technique with 70μm and 250μm thickness, respectively. Interaction studies of the coated graphite with molten uranium at 1450°C for 20 min revealed that Y2O3 coating with SiC interlayer provides physical barrier for uranium-graphite interaction, however, this led to the physical separation of coating layer. Y2O3 coating with Mo interlayer provided superior barrier effect showing no degradation and the coatings remained intact after interaction tests. Therefore, the Mo/Y2O3 coating was found to be a promising solution for minimizing carbon pick-up during uranium/uranium alloy melting.
نوع الوثيقة: article
وصف الملف: electronic resource
اللغة: English
تدمد: 1738-5733
Relation: http://www.sciencedirect.com/science/article/pii/S1738573322005927; https://doaj.org/toc/1738-5733
DOI: 10.1016/j.net.2022.12.025
URL الوصول: https://doaj.org/article/c87f55332c494cdba376aa57a12f51ee
رقم الانضمام: edsdoj.87f55332c494cdba376aa57a12f51ee
قاعدة البيانات: Directory of Open Access Journals
الوصف
تدمد:17385733
DOI:10.1016/j.net.2022.12.025