Academic Journal
Crystal structure of bis(N-tert-butylbenzamidinium) hexachloridozirconate(IV) dichloromethane disolvate
| العنوان: | Crystal structure of bis(N-tert-butylbenzamidinium) hexachloridozirconate(IV) dichloromethane disolvate |
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| المؤلفون: | Zhi-Hao Jiang, Jian-Ping Zhao, Xiu-Ming Ma, Sheng-Di Bai |
| المصدر: | Acta Crystallographica Section E: Crystallographic Communications, Vol 72, Iss 4, Pp 432-435 (2016) |
| بيانات النشر: | International Union of Crystallography, 2016. |
| سنة النشر: | 2016 |
| المجموعة: | LCC:Crystallography |
| مصطلحات موضوعية: | crystal structure, benzamidinium, zirconate, N—H...Cl hydrogen bonds, Crystallography, QD901-999 |
| الوصف: | In the ZrIV complex anion of the title complex salt, [(C4H9)HNC(C6H5)NH2]2[ZrCl6]·2CH2Cl2, the ZrIV cation, located on an inversion centre, is coordinated by six Cl− anions in a distorted octahedral geometry with Zr—Cl distances in the range 2.433 (2)–2.4687 (19) Å; in the amidinium cation, the dihedral angle between the aromatic ring and [NCN] plane is 43.3 (4)°. In the crystal, the amidinium cations and [ZrCl6]2− anions are linked by N—H...Cl hydrogen bonds, forming a two-dimensional network extending along the b axis; two dichloromethane solvent molecules are linked by a pair of weak C—H...Cl hydrogen bonds, forming a centrosymmetric [CHCl]2 six-membered ring. |
| نوع الوثيقة: | article |
| وصف الملف: | electronic resource |
| اللغة: | English |
| تدمد: | 2056-9890 20569890 |
| Relation: | http://scripts.iucr.org/cgi-bin/paper?S2056989016003030; https://doaj.org/toc/2056-9890 |
| DOI: | 10.1107/S2056989016003030 |
| URL الوصول: | https://doaj.org/article/79dd3b384bde4abd95557f6f17389c10 |
| رقم الانضمام: | edsdoj.79dd3b384bde4abd95557f6f17389c10 |
| قاعدة البيانات: | Directory of Open Access Journals |
Full Text Finder | تدمد: | 20569890 |
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| DOI: | 10.1107/S2056989016003030 |