Academic Journal

Surface polarization profile of ferroelectric thin films probed by X-ray standing waves and photoelectron spectroscopy

التفاصيل البيبلوغرافية
العنوان: Surface polarization profile of ferroelectric thin films probed by X-ray standing waves and photoelectron spectroscopy
المؤلفون: Le Phuong Hoang, Irena Spasojevic, Tien-Lin Lee, David Pesquera, Kai Rossnagel, Jörg Zegenhagen, Gustau Catalan, Ivan A. Vartanyants, Andreas Scherz, Giuseppe Mercurio
المصدر: Scientific Reports, Vol 14, Iss 1, Pp 1-19 (2024)
بيانات النشر: Nature Portfolio, 2024.
سنة النشر: 2024
المجموعة: LCC:Medicine
LCC:Science
مصطلحات موضوعية: Ferroelectric polarization, X-ray standing wave, X-ray photoelectron spectroscopy, Medicine, Science
الوصف: Abstract Understanding the mechanisms underlying a stable polarization at the surface of ferroelectric thin films is of particular importance both from a fundamental point of view and to achieve control of the surface polarization itself. In this study, we demonstrate that the X-ray standing wave technique allows the surface polarization profile of a ferroelectric thin film, as opposed to the average film polarity, to be probed directly. The X-ray standing wave technique provides the average Ti and Ba atomic positions, along the out-of-plane direction, near the surface of three differently strained $$\mathrm {BaTiO_3}$$ thin films. This technique gives direct access to the local ferroelectric polarization at and below the surface. By employing X-ray photoelectron spectroscopy, a detailed overview of the oxygen-containing species adsorbed on the surface is obtained. The different amplitude and orientation of the local ferroelectric polarizations are associated with surface charges attributed to different type, amount and spatial distribution of the oxygen-containing adsorbates.
نوع الوثيقة: article
وصف الملف: electronic resource
اللغة: English
تدمد: 2045-2322
Relation: https://doaj.org/toc/2045-2322
DOI: 10.1038/s41598-024-72805-1
URL الوصول: https://doaj.org/article/7994dc44847c4683a2727cf9f0447eca
رقم الانضمام: edsdoj.7994dc44847c4683a2727cf9f0447eca
قاعدة البيانات: Directory of Open Access Journals
الوصف
تدمد:20452322
DOI:10.1038/s41598-024-72805-1