Academic Journal
Poly[μ-aqua-diaqua(μ3-1H-benzimidazole-5-carboxylato-κ3N3:O,O′)(μ2-1H-benzimidazole-5-carboxylato-κ3N3:O:O′)-μ5-sulfato-μ4-sulfato-tricadmium]
| العنوان: | Poly[μ-aqua-diaqua(μ3-1H-benzimidazole-5-carboxylato-κ3N3:O,O′)(μ2-1H-benzimidazole-5-carboxylato-κ3N3:O:O′)-μ5-sulfato-μ4-sulfato-tricadmium] |
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| المؤلفون: | Lai-Chen Chen, Shu-Min Huo, Hao-Zhao Chen, Ya-Qing Yang, Rong-Hua Zeng |
| المصدر: | Acta Crystallographica Section E, Vol 67, Iss 9, Pp m1312-m1313 (2011) |
| بيانات النشر: | International Union of Crystallography, 2011. |
| سنة النشر: | 2011 |
| المجموعة: | LCC:Crystallography |
| مصطلحات موضوعية: | Crystallography, QD901-999 |
| الوصف: | The asymmetric unit of the title compound, [Cd3(C8H5N2O2)2(SO4)2(H2O)3]n, contains three CdII ions, two sulfate anions, two 1H-benzimidazole-5-carboxylate (H2bic) ligands and three coordinated water molecules. One CdII ion is six-coordinated and exhibits a distorted octahedral geometry, while the other two CdII ions are seven-coordinated, displaying a distorted pentagonal–bipyramidal geometry. The CdII ions are bridged by two types of sulfate anions, producing inorganic chains along [100]. These chains are further connected by the H2bic ligands, leading to a three-dimensional framework. N—H...O and O—H...O hydrogen bonds and π–π interactions between the imidazole and benzene rings [centroid–centroid distances = 3.953 (2), 3.507 (2), 3.407 (2) and 3.561 (2) Å] further stabilize the crystal structure. |
| نوع الوثيقة: | article |
| وصف الملف: | electronic resource |
| اللغة: | English |
| تدمد: | 16005368 1600-5368 |
| Relation: | http://scripts.iucr.org/cgi-bin/paper?S1600536811034477; https://doaj.org/toc/1600-5368 |
| DOI: | 10.1107/S1600536811034477 |
| URL الوصول: | https://doaj.org/article/7574c01586a64b2b8dbe488180b7be95 |
| رقم الانضمام: | edsdoj.7574c01586a64b2b8dbe488180b7be95 |
| قاعدة البيانات: | Directory of Open Access Journals |
Full Text Finder | تدمد: | 16005368 |
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| DOI: | 10.1107/S1600536811034477 |