التفاصيل البيبلوغرافية
| العنوان: |
Electrochemical behaviors and electrochemical determination of carbamazepine at ionic liquid modified carbon paste electrode in the presence of sodium dodecyl sulfate |
| المؤلفون: |
Liu Li-Hong, Duan Cheng-Qian, Gao Zuo-Ning |
| المصدر: |
Journal of the Serbian Chemical Society, Vol 77, Iss 4, Pp 483-496 (2012) |
| بيانات النشر: |
Serbian Chemical Society, 2012. |
| سنة النشر: |
2012 |
| المجموعة: |
LCC:Chemistry |
| مصطلحات موضوعية: |
Carbamazepine, Sodium dodecyl sulfate, Ionic liquid modified carbon paste electrode, Electrochemistry, Chemistry, QD1-999 |
| الوصف: |
The electrochemical behavior and electrochemical determination of carbamazepine (CBZ) at hydrophobic ionic liquid 1-Benzyl-3-Methylimidazole hexafluorophosphate ([BnMIM]PF6) modified carbon paste electrode ([BnMIM]PF6/CPE) in the presence of sodium dodecyl sulfate (SDS) were investigated. A well-defined and sensitive oxidation peak was observed at [BnMIM]PF6/CPE in the presence of SDS and 0.10 M phosphate buffer solution (pH 6.80). The oxidation peak current of CBZ increased significantly at [BnMIM]PF6/CPE in the presence of SDS compared with that in the absence of SDS at carbon paste electrode. It suggested that both SDS and [BnMIM]PF6/CPE show an obvious enhancing effect on the electrochemical oxidation of CBZ. The electrochemical kinetic parameters for CBZ at [BnMIM]PF6/CPE in aqueous SDS solutions were also determined by Chronocoulometry and Chronoamperometry. Finally, the experimental conditions were optimized, and a new electrochemical method of determination for CBZ had been established. The oxidation peak current was linearly dependent on CBZ concentration in the range of 7.0 μM to 0.7 mM with a detection limit of 0.98 μM (signal to noice ratio, S/N = 3). The relative standard deviation for six determinations of 0.10 mM CBZ was between 1.40 and 2.13%. The proposed method was applied in the determination of CBZ in commercial tablet samples. |
| نوع الوثيقة: |
article |
| وصف الملف: |
electronic resource |
| اللغة: |
English |
| تدمد: |
0352-5139 |
| Relation: |
https://doaj.org/toc/0352-5139 |
| DOI: |
10.2298/JSC110420188L |
| URL الوصول: |
https://doaj.org/article/752818677a2147419ce635606a269c82 |
| رقم الانضمام: |
edsdoj.752818677a2147419ce635606a269c82 |
| قاعدة البيانات: |
Directory of Open Access Journals |