التفاصيل البيبلوغرافية
| العنوان: |
Vapor-Phase Oxidant-Free Dehydrogenation of 2,3- and 1,4-Butanediol over Cu/SiO2 Catalyst Prepared by Crown-Ether-Assisted Impregnation |
| المؤلفون: |
Enggah Kurniawan, Shuya Hosaka, Masayuki Kobata, Yasuhiro Yamada, Satoshi Sato |
| المصدر: |
Chemistry, Vol 5, Iss 1, Pp 406-421 (2023) |
| بيانات النشر: |
MDPI AG, 2023. |
| سنة النشر: |
2023 |
| المجموعة: |
LCC:Chemistry |
| مصطلحات موضوعية: |
organic additive, crown ether, Cu/SiO2 catalyst, butanediol dehydrogenation, Chemistry, QD1-999 |
| الوصف: |
A silica-supported copper (Cu/SiO2) catalyst containing highly dispersed Cu nanoparticles was prepared via a crown-ether-assisted impregnation method. A 12-crown-4-ether-assisted Cu/SiO2 catalyst outperformed several Cu/SiO2 catalysts prepared with various organic additives in the dehydrogenation of 2,3- and 1,4-butanediol. It was found that the catalytic activity, i.e., the formation rate of acetoin from 2,3-butanediol and that of γ-butyrolactone from 1,4-butanediol, was proportional to the copper surface area. |
| نوع الوثيقة: |
article |
| وصف الملف: |
electronic resource |
| اللغة: |
English |
| تدمد: |
2624-8549 |
| Relation: |
https://www.mdpi.com/2624-8549/5/1/30; https://doaj.org/toc/2624-8549 |
| DOI: |
10.3390/chemistry5010030 |
| URL الوصول: |
https://doaj.org/article/a6ef0ae77e0a41149c9c2d5ca761b155 |
| رقم الانضمام: |
edsdoj.6ef0ae77e0a41149c9c2d5ca761b155 |
| قاعدة البيانات: |
Directory of Open Access Journals |