التفاصيل البيبلوغرافية
| العنوان: |
Interface engineering of Fe-Co3N/CoP composite with N-doped C by using soybean: Fabrication of efficient electrocatalysts for oxygen evolution reaction |
| المؤلفون: |
Longqing Gao, Xiumin Li, Chao Tang, Tianshuo Xie, Zhengkun Xie, Haimei Li, Guoqing Guan, Jie Liu, Keyong Tang |
| المصدر: |
Carbon Resources Conversion, Vol 6, Iss 2, Pp 98-105 (2023) |
| بيانات النشر: |
KeAi Communications Co., Ltd., 2023. |
| سنة النشر: |
2023 |
| المجموعة: |
LCC:Chemical technology |
| مصطلحات موضوعية: |
Water electrolysis, Oxygen evolution reaction, Co3N, CoP, Co-N-C, Soybean template, Chemical technology, TP1-1185 |
| الوصف: |
Soybean can serve as an efficient carbon and nitrogen source for in-situ fabrication of efficient composite electrocatalysts with conductive nitrogen-doped carbon (N-C) material. In this study, the iron-doped cobalt nitride/phosphide (Fe-Co3N/CoP) nanosheet was composited with a conductive N-C material by using soybean as C and N source, as well as NH3 as additional nitrogen source. During the nitridation process of Fe-Co3N, N-C bond was formed as a newly generated Co(Fe)-N-C active sites. Therefore, it fabricates a good microscopic contact interface between the catalyst and carbon material for charge transfer. Besides, the introduction of Fe-CoP by partially phosphating Fe-Co3N further improved the OER activity due to the high catalytic activity of Co sites with high valence state. As a result, the obtained electrocatalyst exhibited overpotentials as low as 285 and 390 mV for supporting 10 and 100 mA/cm−2 current densities. This work indicates that the design of materials with good interfaces could be an effective approach for the preparation of electrocatalysts for water electrolysis. |
| نوع الوثيقة: |
article |
| وصف الملف: |
electronic resource |
| اللغة: |
English |
| تدمد: |
2588-9133 |
| Relation: |
http://www.sciencedirect.com/science/article/pii/S2588913322000734; https://doaj.org/toc/2588-9133 |
| DOI: |
10.1016/j.crcon.2022.12.005 |
| URL الوصول: |
https://doaj.org/article/62449bbda02d49649151963a19c696b4 |
| رقم الانضمام: |
edsdoj.62449bbda02d49649151963a19c696b4 |
| قاعدة البيانات: |
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