Academic Journal
The Effect of the Mid‐Shell Thickness on the Charge‐Carrier Dynamics of the Green‐Light Emitting InP/ZnSe/ZnS Core‐Shell Quantum Dots
| العنوان: | The Effect of the Mid‐Shell Thickness on the Charge‐Carrier Dynamics of the Green‐Light Emitting InP/ZnSe/ZnS Core‐Shell Quantum Dots |
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| المؤلفون: | Dong‐gu Kang, Yu‐Ho Won, Chanho Park, Yongseok Han, Sang Kyu Kim |
| المصدر: | Advanced Materials Interfaces, Vol 11, Iss 2, Pp n/a-n/a (2024) |
| بيانات النشر: | Wiley-VCH, 2024. |
| سنة النشر: | 2024 |
| المجموعة: | LCC:Physics LCC:Technology |
| مصطلحات موضوعية: | charge carrier dynamics, core–shell quantum dots, femtosecond stimulated Raman, transient absorption, Physics, QC1-999, Technology |
| الوصف: | Abstract Ultrafast charge carrier dynamics of green‐light emitting InP/ZnSe/ZnS core–shell quantum dots (QDs) with three different ZnSe thickness of 2.0 nm (gQD‐20), 2.4 nm (gQD‐24), or 3.3 nm (gQD‐33) are interrogated by femtosecond transient absorption (TA) and femtosecond stimulated Raman spectroscopy (FSRS). Auger‐type cooling of hot electron into the band‐edge level of InP is clearly manifested in the TA spectra, giving its time constant of ≈222, 300, or 349 fs for gQD‐20, gQD‐24, or gQD‐33, respectively, indicating that the state‐filling to the 1S(e) of InP is significantly slowed down with the increase of the mid shell thickness. The global analysis of the whole TA spectra turns out to be extremely useful to explain the dynamic behavior of the heterogeneous ensemble of single and/or bi‐ (or multi‐) excitons in the presence of the Stark‐shift. The hole‐relaxation dynamics into the band‐edge 1S (h) of the core InP is revealed in the bleaching dynamics of the FSR bands corresponding to the phonon mode of InP or ZnSe, giving the estimated lifetime of 1.0–1.4 ps for gQD‐20. The hole‐relaxation dynamics by the phonon emission seem to be little sensitive to the ZnSe shell thickness. |
| نوع الوثيقة: | article |
| وصف الملف: | electronic resource |
| اللغة: | English |
| تدمد: | 2196-7350 |
| Relation: | https://doaj.org/toc/2196-7350 |
| DOI: | 10.1002/admi.202300575 |
| URL الوصول: | https://doaj.org/article/618fb63b1f6f47fe940b0e0c400e68f8 |
| رقم الانضمام: | edsdoj.618fb63b1f6f47fe940b0e0c400e68f8 |
| قاعدة البيانات: | Directory of Open Access Journals |
Full Text Finder | تدمد: | 21967350 |
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| DOI: | 10.1002/admi.202300575 |