Academic Journal
Biodegradable Blown Film Composites from Bioplastic and Talc: Effect of Uniaxial Stretching on Mechanical and Barrier Properties
| العنوان: | Biodegradable Blown Film Composites from Bioplastic and Talc: Effect of Uniaxial Stretching on Mechanical and Barrier Properties |
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| المؤلفون: | Debarshi Nath, Akhilesh Kumar Pal, Manjusri Misra, Amar K. Mohanty |
| المصدر: | Macromolecular Materials and Engineering, Vol 308, Iss 12, Pp n/a-n/a (2023) |
| بيانات النشر: | Wiley-VCH, 2023. |
| سنة النشر: | 2023 |
| المجموعة: | LCC:Materials of engineering and construction. Mechanics of materials LCC:Engineering (General). Civil engineering (General) |
| مصطلحات موضوعية: | blown film, crystallinity, poly(butylene succinate‐co‐adipate), uniaxial stretching, water vapor barrier property, Materials of engineering and construction. Mechanics of materials, TA401-492, Engineering (General). Civil engineering (General), TA1-2040 |
| الوصف: | Abstract As public awareness about climate change grows, there is an increase in the research on bioplastic packaging films. This is the first‐ever scientific report on uniaxially stretched biobased‐polybutylene succinate‐co‐adipate (BioPBSA) and talc (15 and 25 wt%) based blown film composites at different stretch ratios (SR). The water vapor barrier properties of BioPBSA+25%Talc film at SR 4 shows an improvement of 40% compared to its unstretched counterpart, while an overall improvement of 48% is observed compared to the unstretched BioPBSA film. The successful dispersion of talc in the BioPBSA matrix, the orientation of talc filler during stretching, and the polymer chains orientation are responsible for such improvement. Additionally, XRD analysis shows that during uniaxial stretching, the crystallinity of the films increases by up to 26% as a result of strain‐induced crystallization, with BioPBSA+25%Talc at SR 4 having the highest crystallinity (≈75%). Furthermore, the inclusion of 25% talc in BioPBSA considerably enhances the tensile modulus by 246% compared to its unstretched counterpart. Hence biodegradable films with balanced barrier and tensile properties may be promising alternatives to petroleum‐based plastic materials used in flexible packaging applications. |
| نوع الوثيقة: | article |
| وصف الملف: | electronic resource |
| اللغة: | English |
| تدمد: | 1439-2054 1438-7492 |
| Relation: | https://doaj.org/toc/1438-7492; https://doaj.org/toc/1439-2054 |
| DOI: | 10.1002/mame.202300214 |
| URL الوصول: | https://doaj.org/article/600382cef3e24271a7f68edbdd1b780d |
| رقم الانضمام: | edsdoj.600382cef3e24271a7f68edbdd1b780d |
| قاعدة البيانات: | Directory of Open Access Journals |
Full Text Finder | تدمد: | 14392054 14387492 |
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| DOI: | 10.1002/mame.202300214 |