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Crystal structure of the [(THF)Cs(μ-η5:η5-Cp′)3Yb]n oligomer

التفاصيل البيبلوغرافية
العنوان: Crystal structure of the [(THF)Cs(μ-η5:η5-Cp′)3Yb]n oligomer
المؤلفون: Daniel N. Huh, Joseph W. Ziller, William J. Evans
المصدر: Acta Crystallographica Section E: Crystallographic Communications, Vol 76, Iss 7, Pp 1131-1135 (2020)
بيانات النشر: International Union of Crystallography, 2020.
سنة النشر: 2020
المجموعة: LCC:Crystallography
مصطلحات موضوعية: lanthanide, caesium, cyclopentadienide, oligomer, crystal structure, Crystallography, QD901-999
الوصف: The green compound poly[(tetrahydrofuran)tris[μ-η5:η5-1-(trimethylsilyl)cyclopentadienyl]caesium(I)ytterbium(II)], [CsYb(C8H13Si)3(C4H8O)]n or [(THF)Cs(μ-η5:η5-Cp′)3YbII]n was synthesized by reduction of a red THF solution of (C5H4SiMe3)3YbIII with excess Cs metal and identified by X-ray diffraction. The compound crystallizes as a two-dimensional array of hexagons with alternating CsI and YbII ions at the vertices and cyclopentadienyl groups bridging each edge. This, based off the six-electron cyclopentadienyl rings occupying three coordination positions, gives a formally nine-coordinate tris(cyclopentadienyl) coordination environment to Yb and the Cs is ten-coordinate due to the three cyclopentadienyl rings and a coordinated molecule of THF. The complex comprises layers of Cs3Yb3 hexagons with THF ligands and Me3Si groups in between the layers. The Yb—C metrical parameters are consistent with a 4f14 YbII electron configuration.
نوع الوثيقة: article
وصف الملف: electronic resource
اللغة: English
تدمد: 2056-9890
20569890
Relation: http://scripts.iucr.org/cgi-bin/paper?S2056989020008051; https://doaj.org/toc/2056-9890
DOI: 10.1107/S2056989020008051
URL الوصول: https://doaj.org/article/584eda951d104b3c8f0f53ce672b5581
رقم الانضمام: edsdoj.584eda951d104b3c8f0f53ce672b5581
قاعدة البيانات: Directory of Open Access Journals
الوصف
تدمد:20569890
DOI:10.1107/S2056989020008051