التفاصيل البيبلوغرافية
| العنوان: |
Basketing nanopalladium into calix[4]pyrrole as an efficient catalyst for Mizoroki-Heck reaction |
| المؤلفون: |
Anita Kongor, Manthan Panchal, Viren Mehta, Keyur Bhatt, Dehin Bhagat, Devayani Tipre, Vinod K. Jain |
| المصدر: |
Arabian Journal of Chemistry, Vol 10, Iss 8, Pp 1125-1135 (2017) |
| بيانات النشر: |
Elsevier, 2017. |
| سنة النشر: |
2017 |
| المجموعة: |
LCC:Chemistry |
| مصطلحات موضوعية: |
Calix[4]pyrrole tetrahydrazide, Palladium nanoparticles, Nanocatalyst, Mizoroki-Heck reaction, Recyclability, Chemistry, QD1-999 |
| الوصف: |
An approach to synthesize calix[4]pyrrole protected palladium nanoparticles (PdNPs) employed for catalytic Mizoroki-Heck C-C coupling reaction is reported. The nanoparticles are synthesized in water using novel calix[4]pyrrole tetrahydrazide (CPTH) as a reducing as well as stabilizing agent which is a proficient “one-pot” synthesis discouraging the need of an external stabilizer. CPTH-PdNPs have been characterized and studied by UV–Vis spectroscopy, Fourier transform infrared, transmission electron microscopy, energy‐dispersive X‐ray and powder X‐ray diffraction. The synthesized palladium nanoparticles with a size range of 5–9 nm show an efficient catalytic activity for Heck cross-coupling reactions giving good yields within short reaction time in comparison with conventional palladium catalyst. Also, a good degree of recyclability is shown by the nanocatalyst with five consecutive catalytic cycles. CPTH-PdNPs also exhibit a potential antimicrobial activity against gram-negative bacteria which shows the biological applicability of the synthesized CPTH-PdNPs. |
| نوع الوثيقة: |
article |
| وصف الملف: |
electronic resource |
| اللغة: |
English |
| تدمد: |
1878-5352 |
| Relation: |
http://www.sciencedirect.com/science/article/pii/S1878535216300971; https://doaj.org/toc/1878-5352 |
| DOI: |
10.1016/j.arabjc.2016.06.019 |
| URL الوصول: |
https://doaj.org/article/51b8906229224d5894506f473fca7332 |
| رقم الانضمام: |
edsdoj.51b8906229224d5894506f473fca7332 |
| قاعدة البيانات: |
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