Academic Journal
Crystal structure of S-n-octyl 3-(1-phenylethylidene)dithiocarbazate and of its bis-chelated nickel(II) complex
| العنوان: | Crystal structure of S-n-octyl 3-(1-phenylethylidene)dithiocarbazate and of its bis-chelated nickel(II) complex |
|---|---|
| المؤلفون: | Sultana Shakila Khan, Md. Belayet Hossain Howlader, Md. Chanmiya Sheikh, Ryuta Miyatake, Ennio Zangrando, Md. Rezaul Haque Ansary |
| المصدر: | Acta Crystallographica Section E: Crystallographic Communications, Vol 79, Iss 12, Pp 1137-1141 (2023) |
| بيانات النشر: | International Union of Crystallography, 2023. |
| سنة النشر: | 2023 |
| المجموعة: | LCC:Crystallography |
| مصطلحات موضوعية: | crystal structure, dithiocarbazate ligand, niii complex, cis configuration complex, octyl alkyl chain, Crystallography, QD901-999 |
| الوصف: | The nitrogen–sulfur Schiff base proligand S-n-octyl 3-(1-phenylethylidene)dithiocarbazate, C17H26N2S2 (HL), was prepared by reaction of S-octyl dithiocarbamate with acetophenone. Treatment of HL with nickel acetate yielded the complex bis[S-n-octyl 3-(1-phenylethylidene)dithiocarbazato]nickel(II), [Ni(C17H25N2S2)2] (NiL2), which was shown to adopt a tetrahedrally distorted cis-square-planar coordination geometry, with the NiSN planes of the two ligands forming a dihedral angle of 21.66 (6)°. Changes in the geometry of the L ligand upon chelation of Ni2+ are described, involving a ca 180° rotation around the N(azomethine)—C(thiolate) bond. |
| نوع الوثيقة: | article |
| وصف الملف: | electronic resource |
| اللغة: | English |
| تدمد: | 2056-9890 20569890 |
| Relation: | http://scripts.iucr.org/cgi-bin/paper?S2056989023009726; https://doaj.org/toc/2056-9890 |
| DOI: | 10.1107/S2056989023009726 |
| URL الوصول: | https://doaj.org/article/d3fe2c93b88f4cb98f2d4216e2fe60a2 |
| رقم الانضمام: | edsdoj.3fe2c93b88f4cb98f2d4216e2fe60a2 |
| قاعدة البيانات: | Directory of Open Access Journals |
Full Text Finder | تدمد: | 20569890 |
|---|---|
| DOI: | 10.1107/S2056989023009726 |