التفاصيل البيبلوغرافية
| العنوان: |
Imidazolium bromide substituted magnesium phthalocyanine polymers: New promising materials for CO2 conversion |
| المؤلفون: |
Benedetto Taormina, Rémy Jouclas, Vittorio Marsala, Michelangelo Gruttadauria, Francesco Giacalone, Carmela Aprile |
| المصدر: |
Journal of CO2 Utilization, Vol 85, Iss , Pp 102875- (2024) |
| بيانات النشر: |
Elsevier, 2024. |
| سنة النشر: |
2024 |
| المجموعة: |
LCC:Technology |
| مصطلحات موضوعية: |
Carbon dioxide fixation, Bifunctional catalyst, Mg-phthalocyanines, Cyclic carbonates, Technology |
| الوصف: |
The conversion of CO2 with epoxides into the corresponding cyclic carbonates represents a green approach to transform a waste into value-added products. To promote this conversion, a catalyst in needed. This study presents the synthesis of two cross-linked materials composed of magnesium phthalocyanine and imidazolium bromide moieties: MgPc-BIBI-Br and MgPc-SIBI-Br. Magnesium phthalocyanines are cost-effective and versatile catalysts, synthesized in high yield from low-cost precursors and can be easily modified for specific needs. Imidazolium bromide groups play a crucial role as well, acting as a nucleophile source essential to promote the ring-opening process of the epoxide. The materials have been extensively characterized through analytical and spectroscopic techniques and tested as catalysts in the conversion of epichlorohydrin into 4-chloromethyl-1,3-dioxalan-2-one. They both achieved excellent catalytic performance (maximal TON values of 3070 for MgPc-SIBI-Br and 1903 for MgPc-BIBI-Br) and recyclability (both recyclable at least for 4 cycles). The reported results represent an improvement if compared to similar materials already reported in the literature in which the addition of external nucleophilic species (e.g. TBAB, BMIM-Br, etc.) is needed. To the best of our knowledge, this work is the first example in which imidazolium bromide and magnesium phthalocyanine moieties are combined in bifunctional polymeric materials that convert CO2 into cyclic carbonates via heterogeneous catalysis. |
| نوع الوثيقة: |
article |
| وصف الملف: |
electronic resource |
| اللغة: |
English |
| تدمد: |
2212-9839 |
| Relation: |
http://www.sciencedirect.com/science/article/pii/S2212982024002105; https://doaj.org/toc/2212-9839 |
| DOI: |
10.1016/j.jcou.2024.102875 |
| URL الوصول: |
https://doaj.org/article/39b78a15a34f4ad0997c30b814067a0f |
| رقم الانضمام: |
edsdoj.39b78a15a34f4ad0997c30b814067a0f |
| قاعدة البيانات: |
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