Academic Journal
One-dimensional lanthanide chain bridged by nitronyl nitroxide radical ligand: structure and magnetic properties
العنوان: | One-dimensional lanthanide chain bridged by nitronyl nitroxide radical ligand: structure and magnetic properties |
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المؤلفون: | Dong Hui Yang, Zhu Me |
المصدر: | E3S Web of Conferences, Vol 185, p 04052 (2020) |
بيانات النشر: | EDP Sciences, 2020. |
سنة النشر: | 2020 |
المجموعة: | LCC:Environmental sciences |
مصطلحات موضوعية: | Environmental sciences, GE1-350 |
الوصف: | In order to synthesize the molecular magnetic material, the complex{Nd(hfac)3(NIT-5MeThien)}n(NIT-5MeThien=2-(5-Methyl-2ˊ-thienyl)-5--4,4,5,5-tetramethyl-imidazoline-1-oxyl-3-oxide) has been synthesized by the reaction using radical ligand and Nd(hfac)3•2H2O. X-ray diffraction analysis showed that the compound belongs to the monoclinic system and constituted by Nd(hfac)3 and NIT-5MeThien to obtain a one-dimensional chain which nitroxide radical acted as a bridged ligand through the N-O groups. Variable temperature magnetization of complex was shown the antiferromagnetic interaction between Nd(III) ion and nitroxide radical. |
نوع الوثيقة: | article |
وصف الملف: | electronic resource |
اللغة: | English French |
تدمد: | 2267-1242 20201850 |
Relation: | https://www.e3s-conferences.org/articles/e3sconf/pdf/2020/45/e3sconf_iceeb2020_04052.pdf; https://doaj.org/toc/2267-1242 |
DOI: | 10.1051/e3sconf/202018504052 |
URL الوصول: | https://doaj.org/article/2bbd6ebeb74f41eab44e1ab309382452 |
رقم الانضمام: | edsdoj.2bbd6ebeb74f41eab44e1ab309382452 |
قاعدة البيانات: | Directory of Open Access Journals |
تدمد: | 22671242 20201850 |
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DOI: | 10.1051/e3sconf/202018504052 |