Academic Journal

Poly[[diaqua-μ3-citrato-praseodymium(III)] monohydrate]

التفاصيل البيبلوغرافية
العنوان: Poly[[diaqua-μ3-citrato-praseodymium(III)] monohydrate]
المؤلفون: Li-Jun Han, Yuan-Fu Deng, Seik Weng Ng
المصدر: Acta Crystallographica Section E, Vol 67, Iss 7, Pp m981-m981 (2011)
بيانات النشر: International Union of Crystallography, 2011.
سنة النشر: 2011
المجموعة: LCC:Crystallography
مصطلحات موضوعية: Crystallography, QD901-999
الوصف: In the coordination polymer, {[Pr(C6H5O7)(H2O)2]·H2O}n, seven of the nine coordination sites of the monocapped square-antiprismatic geometry are occupied by three O atoms of the same citrate trianion (an O atom of the hydroxy unit and the formally single-bond O atoms from two carboxyl units). Two other coordination sites are occupied by the O atoms of a chelating carboxyl unit of another citrate; one of these atoms is additionally involved in bridging. The seventh coordination site is occupied by the O atom of the formally double-bond O atom of a neighboring citrate. The remaining two coordination sites are occupied by water molecules. The citrate functions in a μ3-bridging mode, connecting the metal atoms into a ribbon structure parallel to [010]. The structure is consolidated into a three-dimensional network by O—H...O hydrogen bonds.
نوع الوثيقة: article
وصف الملف: electronic resource
اللغة: English
تدمد: 16005368
1600-5368
Relation: http://scripts.iucr.org/cgi-bin/paper?S1600536811023804; https://doaj.org/toc/1600-5368
DOI: 10.1107/S1600536811023804
URL الوصول: https://doaj.org/article/1fd4c4b202fc40f4b90f115bc674ae88
رقم الانضمام: edsdoj.1fd4c4b202fc40f4b90f115bc674ae88
قاعدة البيانات: Directory of Open Access Journals
الوصف
تدمد:16005368
DOI:10.1107/S1600536811023804