Academic Journal
Poly[[diaqua-μ3-citrato-praseodymium(III)] monohydrate]
العنوان: | Poly[[diaqua-μ3-citrato-praseodymium(III)] monohydrate] |
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المؤلفون: | Li-Jun Han, Yuan-Fu Deng, Seik Weng Ng |
المصدر: | Acta Crystallographica Section E, Vol 67, Iss 7, Pp m981-m981 (2011) |
بيانات النشر: | International Union of Crystallography, 2011. |
سنة النشر: | 2011 |
المجموعة: | LCC:Crystallography |
مصطلحات موضوعية: | Crystallography, QD901-999 |
الوصف: | In the coordination polymer, {[Pr(C6H5O7)(H2O)2]·H2O}n, seven of the nine coordination sites of the monocapped square-antiprismatic geometry are occupied by three O atoms of the same citrate trianion (an O atom of the hydroxy unit and the formally single-bond O atoms from two carboxyl units). Two other coordination sites are occupied by the O atoms of a chelating carboxyl unit of another citrate; one of these atoms is additionally involved in bridging. The seventh coordination site is occupied by the O atom of the formally double-bond O atom of a neighboring citrate. The remaining two coordination sites are occupied by water molecules. The citrate functions in a μ3-bridging mode, connecting the metal atoms into a ribbon structure parallel to [010]. The structure is consolidated into a three-dimensional network by O—H...O hydrogen bonds. |
نوع الوثيقة: | article |
وصف الملف: | electronic resource |
اللغة: | English |
تدمد: | 16005368 1600-5368 |
Relation: | http://scripts.iucr.org/cgi-bin/paper?S1600536811023804; https://doaj.org/toc/1600-5368 |
DOI: | 10.1107/S1600536811023804 |
URL الوصول: | https://doaj.org/article/1fd4c4b202fc40f4b90f115bc674ae88 |
رقم الانضمام: | edsdoj.1fd4c4b202fc40f4b90f115bc674ae88 |
قاعدة البيانات: | Directory of Open Access Journals |
تدمد: | 16005368 |
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DOI: | 10.1107/S1600536811023804 |