التفاصيل البيبلوغرافية
| العنوان: |
Boron and nitrogen codoped carbon nanohorn-supported Pt nanocrystals as highly-efficient methanol oxidation electrocatalysts |
| المؤلفون: |
Xiangjie Guo, Qi Wang, Haiyan He, Huajie Huang |
| المصدر: |
Journal of Materials Research and Technology, Vol 19, Iss , Pp 722-731 (2022) |
| بيانات النشر: |
Elsevier, 2022. |
| سنة النشر: |
2022 |
| المجموعة: |
LCC:Mining engineering. Metallurgy |
| مصطلحات موضوعية: |
Platinum, Carbon nanohorns, Codoping, Electrocatalysts, Methanol oxidation, Mining engineering. Metallurgy, TN1-997 |
| الوصف: |
The large-scale commercialization of direct methanol fuel cells (DMFCs) largely depends on the design and synthesis of advanced Pt-based anode catalysts with excellent electrocatalytic performance and acceptable costs. Herein, we propose a controllable and scalable method to the construction of ultrafine Pt nanocrystals supported by boron and nitrogen codoped carbon nanohorns (Pt/BN-CNH) as electrocatalysts for methanol oxidation reaction. The as-derived Pt/BN-CNH architectures are endowed with a series of interesting physicochemical properties, such as accessible internal pores, numerous active conical tips, coexistence of B and N atoms, and homogeneous Pt distribution. Consequently, the resulting Pt/BN-CNH catalysts present high catalytic activity, reliable long-term stability as well as strong antipoisoning capacity towards methanol oxidation, all of which are superior to those of conventional Pt/carbon black, Pt/carbon nanotube, Pt/graphene and Pt/undoped CNH catalysts, thus offering great potentials in the next-generation DMFC devices. |
| نوع الوثيقة: |
article |
| وصف الملف: |
electronic resource |
| اللغة: |
English |
| تدمد: |
2238-7854 |
| Relation: |
http://www.sciencedirect.com/science/article/pii/S2238785422007499; https://doaj.org/toc/2238-7854 |
| DOI: |
10.1016/j.jmrt.2022.05.088 |
| URL الوصول: |
https://doaj.org/article/e1d31b029c0646ed8245d827f14a4e94 |
| رقم الانضمام: |
edsdoj.1d31b029c0646ed8245d827f14a4e94 |
| قاعدة البيانات: |
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