Academic Journal
Propriedades texturais e catalíticas de óxidos de ferro contendo cromo e cobre Textural and catalytic properties of chromium and copper-doped iron oxides
العنوان: | Propriedades texturais e catalíticas de óxidos de ferro contendo cromo e cobre Textural and catalytic properties of chromium and copper-doped iron oxides |
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المؤلفون: | Marluce Oliveira da Guarda Souza, Emerentino Brazil Quadro, Maria do Carmo Rangel |
المصدر: | Química Nova, Vol 21, Iss 4, Pp 428-433 (1998) |
بيانات النشر: | Sociedade Brasileira de Química, 1998. |
سنة النشر: | 1998 |
المجموعة: | LCC:Chemistry |
مصطلحات موضوعية: | iron oxides, copper-doped catalysts, chromium-doped catalysts, Chemistry, QD1-999 |
الوصف: | Chromium and copper-doped hematites were prepared with the aim of studying the synergistic effect of these dopants on the textural and on the catalytic properties of the iron oxides towards the high temperature shift reaction. It was found that the most active catalysts were those with the highest amount of copper. They had the Fe(II)/Fe(III) ratio near the stoichiometric value of magnetite, the highest surface areas under the reactional atmosphere and the greatest tendency to produce the active form; they also were poorly crystalline solids. The best performance was shown by the catalyst with Fe/Cu=10, heated at 300ºC. It can thus be concluded that copper acts both as textural and structural promoter in these catalysts. |
نوع الوثيقة: | article |
وصف الملف: | electronic resource |
اللغة: | English Spanish; Castilian Portuguese |
تدمد: | 0100-4042 1678-7064 |
Relation: | http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40421998000400010; https://doaj.org/toc/0100-4042; https://doaj.org/toc/1678-7064 |
DOI: | 10.1590/S0100-40421998000400010 |
URL الوصول: | https://doaj.org/article/0e546012fcef4e3eaff53738ec95a2c8 |
رقم الانضمام: | edsdoj.0e546012fcef4e3eaff53738ec95a2c8 |
قاعدة البيانات: | Directory of Open Access Journals |
تدمد: | 01004042 16787064 |
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DOI: | 10.1590/S0100-40421998000400010 |