التفاصيل البيبلوغرافية
| العنوان: |
Thioamide-Directed Cp*Co(III)-Catalyzed C–H Allylation of Ferrocenes |
| المؤلفون: |
Zhuo-Zhuo Zhang (1546144), Gang Liao (1725115), Hao-Ming Chen (6293153), Bing-Feng Shi (1546147) |
| سنة النشر: |
2021 |
| المجموعة: |
Smithsonian Institution: Digital Repository |
| مصطلحات موضوعية: |
Biochemistry, Medicine, Developmental Biology, Computational Biology, Environmental Sciences not elsewhere classified, allylating reagents, allylated ferrocene derivatives, allyl carbonates, Ferrocenes Herein, Mechanistic studies, Allylation, ferrocene thioamides, activation, Thioamide-Directed, role, yield, Cp, vinylcyclopropane, thiocarbonyl-directing group |
| الوصف: |
Herein, the first Cp*Co(III)-catalyzed C–H allylation of ferrocene thioamides with allyl carbonates has been developed. This reaction is compatible with a wide range of functional groups, providing various allylated ferrocene derivatives in up to 90% yields. In addition, the C–H allylation protocol is also compatible with the use of vinylcyclopropanes as allylating reagents by merging C–H and C–C activation into one catalytic system. Mechanistic studies revealed that the thiocarbonyl-directing group plays a vital role in C–H activation. |
| نوع الوثيقة: |
article in journal/newspaper |
| اللغة: |
unknown |
| Relation: |
https://figshare.com/articles/journal_contribution/Thioamide-Directed_Cp_Co_III_-Catalyzed_C_H_Allylation_of_Ferrocenes/14211111 |
| DOI: |
10.1021/acs.orglett.1c00533.s001 |
| الاتاحة: |
https://doi.org/10.1021/acs.orglett.1c00533.s001 |
| Rights: |
CC BY-NC 4.0 |
| رقم الانضمام: |
edsbas.FF95226B |
| قاعدة البيانات: |
BASE |