Academic Journal
Fe/Fe 3 C Nanoparticles Embedded in Nitrogen‐Doped Carbon Nanotubes as Multifunctional Electrocatalysts for Oxygen Catalysis and CO 2 Reduction
| العنوان: | Fe/Fe 3 C Nanoparticles Embedded in Nitrogen‐Doped Carbon Nanotubes as Multifunctional Electrocatalysts for Oxygen Catalysis and CO 2 Reduction |
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| المؤلفون: | Jia, Jingchun, Yang, Huijuan, Wang, Genxiang, Huang, Peng, Cai, Pingwei, Wen, Zhenhai |
| المساهمون: | National Natural Science Foundation of China |
| المصدر: | ChemElectroChem ; volume 5, issue 3, page 471-477 ; ISSN 2196-0216 2196-0216 |
| بيانات النشر: | Wiley |
| سنة النشر: | 2017 |
| المجموعة: | Wiley Online Library (Open Access Articles via Crossref) |
| الوصف: | Hybrids of Fe/Fe 3 C embedded in N‐doped carbon nanotubes (Fe/Fe 3 C@NCNTs) are prepared by pyrolyzing mixtures of Fe 3 O 4 nanoparticles and dicyandiamide. The systematic electrochemical study of Fe/Fe 3 C@NCNTs shows a decent catalytic activity toward the oxygen evolution reaction (OER) and the oxygen reduction reaction (ORR). The sample of Fe/Fe 3 C@NCNTs at 750 °C exhibits a remarkably high activity with an onset potential of 1.47 V for the OER, and an onset potential of 0.96 V and half‐wave potential 0.88 V for the ORR, which inspired us to set up a rechargeable Zn‐air battery with such Fe/Fe 3 C@NCNT nanohybrids as the cathode materials, showing a maximum power density of 198 mW cm −2 and long‐term stability after 500 cycles. We also demonstrate that Fe/Fe 3 C@NCNTs present favorable electrocatalytic activity towards the CO 2 reduction reaction (CO 2 RR) with a low onset potential and good selectivity. The major products are a mixture of H 2 and CO gases that can be used for methanol production in the Fischer−Tropsch process. |
| نوع الوثيقة: | article in journal/newspaper |
| اللغة: | English |
| DOI: | 10.1002/celc.201701179 |
| DOI: | 10.1002/celc.201701179/fullpdf |
| الاتاحة: | https://doi.org/10.1002/celc.201701179 https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fcelc.201701179 http://onlinelibrary.wiley.com/wol1/doi/10.1002/celc.201701179/fullpdf |
| Rights: | http://onlinelibrary.wiley.com/termsAndConditions#vor |
| رقم الانضمام: | edsbas.FCC62969 |
| قاعدة البيانات: | BASE |
| DOI: | 10.1002/celc.201701179 |
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