Academic Journal
A Switchable Palladium(II) Trefoil Entangled Tetrahedron with Temperature Dependence and Concentration Independence
| العنوان: | A Switchable Palladium(II) Trefoil Entangled Tetrahedron with Temperature Dependence and Concentration Independence |
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| المؤلفون: | Algar, Jess L., Findlay, James A., Evans, Jack D., Preston, Dan |
| المساهمون: | Australian Research Council |
| المصدر: | Angewandte Chemie International Edition ; volume 61, issue 39 ; ISSN 1433-7851 1521-3773 |
| بيانات النشر: | Wiley |
| سنة النشر: | 2022 |
| المجموعة: | Wiley Online Library (Open Access Articles via Crossref) |
| الوصف: | Self‐assembly makes metallo‐interlocked architectures attractive targets, but being in equilibrium with smaller species means that they can suffer from dilution effects. We show that a junctioned system gives rise to a [Pd 4 (L) 2 ] 8+ trefoil entangled tetrahedron irrespective of concentration. Heating the sample reversibly shifts the equilibrium from the knot to an isomeric non‐interlocked dual metallo‐cycle, demonstrating that thermodynamic equilibria can still be exploited for switching even in the absence of concentration effects. |
| نوع الوثيقة: | article in journal/newspaper |
| اللغة: | English |
| DOI: | 10.1002/anie.202210476 |
| الاتاحة: | http://dx.doi.org/10.1002/anie.202210476 https://onlinelibrary.wiley.com/doi/pdf/10.1002/anie.202210476 https://onlinelibrary.wiley.com/doi/full-xml/10.1002/anie.202210476 |
| Rights: | http://creativecommons.org/licenses/by/4.0/ ; http://creativecommons.org/licenses/by/4.0/ |
| رقم الانضمام: | edsbas.F8FAF5B5 |
| قاعدة البيانات: | BASE |
| DOI: | 10.1002/anie.202210476 |
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