Academic Journal

The Implications of Membranes Used as Separators in Microbial Fuel Cells

التفاصيل البيبلوغرافية
العنوان: The Implications of Membranes Used as Separators in Microbial Fuel Cells
المؤلفون: Jonathan Ramirez-Nava, Mariana Martínez-Castrejón, Rocío Lley García-Mesino, Jazmin Alaide López-Díaz, Oscar Talavera-Mendoza, Alicia Sarmiento-Villagrana, Fernando Rojano, Giovanni Hernández-Flores
المصدر: Membranes; Volume 11; Issue 10; Pages: 738
بيانات النشر: Multidisciplinary Digital Publishing Institute
سنة النشر: 2021
المجموعة: MDPI Open Access Publishing
مصطلحات موضوعية: membranes, microbial fuel cell, proton-exchange membrane, separators
الوصف: Microbial fuel cells (MFCs) are electrochemical devices focused on bioenergy generation and organic matter removal carried out by microorganisms under anoxic environments. In these types of systems, the anodic oxidation reaction is catalyzed by anaerobic microorganisms, while the cathodic reduction reaction can be carried out biotically or abiotically. Membranes as separators in MFCs are the primary requirements for optimal electrochemical and microbiological performance. MFC configuration and operation are similar to those of proton-exchange membrane fuel cells (PEMFCs)—both having at least one anode and one cathode split by a membrane or separator. The Nafion® 117 (NF-117) membrane, made from perfluorosulfonic acid, is a membrane used as a separator in PEMFCs. By analogy of the operation between electrochemical systems and MFCs, NF-117 membranes have been widely used as separators in MFCs. The main disadvantage of this type of membrane is its high cost; membranes in MFCs can represent up to 60% of the MFC’s total cost. This is one of the challenges in scaling up MFCs: finding alternative membranes or separators with low cost and good electrochemical characteristics. The aim of this work is to critically review state-of-the-art membranes and separators used in MFCs. The scope of this review includes: (i) membrane functions in MFCs, (ii) most-used membranes, (iii) membrane cost and efficiency, and (iv) membrane-less MFCs. Currently, there are at least 20 different membranes or separators proposed and evaluated for MFCs, from basic salt bridges to advanced synthetic polymer-based membranes, including ceramic and unconventional separator materials. Studies focusing on either low cost or the use of natural polymers for proton-exchange membranes (PEM) are still scarce. Alternatively, in some works, MFCs have been operated without membranes; however, significant decrements in Coulombic efficiency were found. As the type of membrane affects the performance and total cost of MFCs, it is recommended that research ...
نوع الوثيقة: text
وصف الملف: application/pdf
اللغة: English
Relation: Membrane Applications; https://dx.doi.org/10.3390/membranes11100738
DOI: 10.3390/membranes11100738
الاتاحة: https://doi.org/10.3390/membranes11100738
Rights: https://creativecommons.org/licenses/by/4.0/
رقم الانضمام: edsbas.F2BCA8B9
قاعدة البيانات: BASE
الوصف
DOI:10.3390/membranes11100738