Academic Journal
An Air-Stable Semiconducting Polymer Containing Dithieno[3,2-b:2′,3′-d]arsole
| العنوان: | An Air-Stable Semiconducting Polymer Containing Dithieno[3,2-b:2′,3′-d]arsole |
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| المؤلفون: | Green, J, Han, Y, Kilmurray, R, McLachlan, M, Anthopoulos, T, Heeney, MJ |
| المساهمون: | Engineering and Physical Sciences Research Council |
| المصدر: | 7151 ; 7148 |
| بيانات النشر: | Wiley |
| سنة النشر: | 2016 |
| المجموعة: | Imperial College London: Spiral |
| مصطلحات موضوعية: | arsenic, conjugated polymers, field-effect transistors, molecular electronics, semiconductors, Organic Chemistry, Chemical Sciences |
| الوصف: | © 2016 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA.Arsole-containing conjugated polymers are a practically unexplored class of materials despite the high interest in their phosphole analogues. Herein we report the synthesis of the first dithieno[3,2-b;2′,3′-d]arsole derivative, and demonstrate that it is stable to ambient oxidation in its +3 oxidation state. A soluble copolymer is obtained by a palladium-catalyzed Stille polymerization and demonstrated to be a p-type semiconductor with promising hole mobility, which was evaluated by field-effect transistor measurements. |
| نوع الوثيقة: | article in journal/newspaper |
| اللغة: | unknown |
| تدمد: | 1433-7851 |
| Relation: | Angewandte Chemie - International Edition; http://hdl.handle.net/10044/1/30881; http://dx.doi.org/10.1002/anie.201602491; EP/G037515/1 |
| DOI: | 10.1002/anie.201602491 |
| الاتاحة: | http://hdl.handle.net/10044/1/30881 https://doi.org/10.1002/anie.201602491 |
| Rights: | © 2016 The Authors. Published by Wiley-VCH Verlag GmbH & Co.KGaA. This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited. |
| رقم الانضمام: | edsbas.EFFDD780 |
| قاعدة البيانات: | BASE |
| تدمد: | 14337851 |
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| DOI: | 10.1002/anie.201602491 |