التفاصيل البيبلوغرافية
| العنوان: |
Macrocyclic Hamilton receptor-shuttling dynamics in [2]rotaxanes |
| المؤلفون: |
Maxime Douarre (4774359), Vicente Martí-Centelles (9540362), Cybille Rossy (9540365), Arnaud Tron (842649), Isabelle Pianet (1695466), Nathan D. McClenaghan (1309863) |
| سنة النشر: |
2020 |
| المجموعة: |
Smithsonian Institution: Digital Repository |
| مصطلحات موضوعية: |
Biophysics, Biochemistry, Cell Biology, Genetics, Neuroscience, Pharmacology, Biotechnology, Evolutionary Biology, Cancer, Hematology, Infectious Diseases, Chemical Sciences not elsewhere classified, Physical Sciences not elsewhere classified, Molecular shuttle, rotaxane, hydrogen bonding, dynamic NMR, macrocycle |
| الوصف: |
Inherent movement of a macrocycle comprising a multi-site hydrogen-bonding Hamilton-type receptor in a series of [2]rotaxanes was investigated by dynamic and VT NMR. In these rotaxanes, the varying nature and number of hydrogen-bond motifs and stations on the molecular axles influenced ring dynamics. Triazole stations interact selectively by hydrogen bonding with the isophthalamide amide bonds present in the Hamilton macrocycle and fast shuttling (72 kHz at 25°C) was observed in a two-station variant. |
| نوع الوثيقة: |
article in journal/newspaper |
| اللغة: |
unknown |
| Relation: |
https://figshare.com/articles/journal_contribution/Macrocyclic_Hamilton_receptor-shuttling_dynamics_in_2_rotaxanes/13117649 |
| DOI: |
10.6084/m9.figshare.13117649.v1 |
| الاتاحة: |
https://doi.org/10.6084/m9.figshare.13117649.v1 |
| Rights: |
CC BY 4.0 |
| رقم الانضمام: |
edsbas.EF2E5B65 |
| قاعدة البيانات: |
BASE |