Academic Journal
Siloxane-based linkers in the construction of hydrogen bonded assemblies and porous 3D MOFs
| العنوان: | Siloxane-based linkers in the construction of hydrogen bonded assemblies and porous 3D MOFs |
|---|---|
| المؤلفون: | Delmas, Luke C., Horton, Peter, White, Andrew J.P., Coles, Simon J., Lickiss, Paul D., Davies, Robert P. |
| سنة النشر: | 2017 |
| المجموعة: | University of Southampton: e-Prints Soton |
| الوصف: | A siloxane-based hexacarboxylic acid (L1-H6) has been prepared and applied in MOF construction. L1-H6 itself crystallizes as an unusual interpenetrated 3D hydrogen-bonded framework. Reaction of L1-H6 with Zn(II) gave IMP-18 – a 3D MOF incorporating Si–O–Si functionality. Cleavage of L1-H6 gives a silanol-based triacid which is shown to give a coordination polymer (IMP-19) with Zn(II). |
| نوع الوثيقة: | article in journal/newspaper |
| وصف الملف: | text |
| اللغة: | English |
| Relation: | https://eprints.soton.ac.uk/416076/1/c7cc06022j.pdf; Delmas, Luke C., Horton, Peter, White, Andrew J.P., Coles, Simon J., Lickiss, Paul D. and Davies, Robert P. (2017) Siloxane-based linkers in the construction of hydrogen bonded assemblies and porous 3D MOFs. Chemical Communications, 2017 (53), 12524-12527. (doi:10.1039/c7cc06022j ). |
| الاتاحة: | https://eprints.soton.ac.uk/416076/ https://eprints.soton.ac.uk/416076/1/c7cc06022j.pdf |
| Rights: | cc_by_4 |
| رقم الانضمام: | edsbas.EE8792C2 |
| قاعدة البيانات: | BASE |
| الوصف غير متاح. |