Academic Journal
Borylated Subphthalocyanines: Versatile Precursors for the Preparation of Functional Bowl-Shaped Aromatics
| العنوان: | Borylated Subphthalocyanines: Versatile Precursors for the Preparation of Functional Bowl-Shaped Aromatics |
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| المؤلفون: | Gómez Gómez, Marta, Labella Santodomingo, Jorge, Torres Cebada, Tomás |
| المساهمون: | UAM. Departamento de Química Orgánica |
| بيانات النشر: | Wiley |
| سنة النشر: | 2023 |
| المجموعة: | Universidad Autónoma de Madrid (UAM): Biblos-e Archivo |
| مصطلحات موضوعية: | Borylation, Bowl-shaped molecules, Cross-coupling, Porphyrinoid, Subphthalocyanine, Química |
| الوصف: | The peripheral borylation of porphyrinoids has become a key step to prepare advanced functional materials. This study reports the synthesis, electronic properties, and reactivity of borylated subphthalocyanines. These compounds, which are prepared by Suzuki–Miyaura borylation in excellent yields, are easily purified, display a great stability, and serve as powerful starting materials for the post-functionalization of SubPcs via cross-coupling reactions. Remarkably, this novel approach is more efficient than the methodologies already described and enables the preparation of exotic systems, such as SubPc dimeric species linked by C−C bonds, which are not accessible so far and present promising properties for optoelectronic devices ; We gratefully acknowledge financial support from MICINN (PID2020-116490GB-I00 and TED2021-131255B-C43), the Comunidad de Madrid and the Spanish State through the Recovery, Transformation and Resilience Plan [“MATERIALES DISRUPTIVOS BIDIMENSIONALES (2D)” (MAD2D-CM)-MRR MATERIALES AVANZADOS], and the European Union through the Next Generation EU funds). IMDEA Nanociencia acknowledges support from the Severo Ochoa’ Programme for Centres of Excellence in R&D (MINECO, Grant SEV2016-0686). J.L. acknowledges MECD, Spain, for a F.P.U. Fellowship |
| نوع الوثيقة: | article in journal/newspaper |
| وصف الملف: | application/pdf |
| اللغة: | English |
| Relation: | Chemistry - A European Journal; https://doi.org/10.1002/chem.202301782; Gobierno de España. TED2021-131255B-C43; Comunidad de Madrid. MAD2D-CM; Gobierno de España. SEV-2016-0686; Chemistry A European Journal 29.1 (2023): e202301782; 0947-6539 (print); 1521-3765 (online); http://hdl.handle.net/10486/708420; e202301782-1; e202301782-5; 29 |
| DOI: | 10.1002/chem.202301782 |
| الاتاحة: | http://hdl.handle.net/10486/708420 https://doi.org/10.1002/chem.202301782 |
| Rights: | © 2023 The Authors ; Reconocimiento ; openAccess |
| رقم الانضمام: | edsbas.ECF70DF8 |
| قاعدة البيانات: | BASE |
| DOI: | 10.1002/chem.202301782 |
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