Academic Journal
Bis-Cyclooctatetraenyl Thulium(II): Highly Reducing Lanthanide Sandwich Single-Molecule Magnets
| العنوان: | Bis-Cyclooctatetraenyl Thulium(II): Highly Reducing Lanthanide Sandwich Single-Molecule Magnets |
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| المؤلفون: | Moutet, Jules, Schleinitz, Jules, La Droitte, Leo, Tricoire, Maxime, Pointillart, Fabrice, Gendron, Frédéric, Simler, Thomas, Clavaguéra, Carine, Le Guennic, Boris, Cador, Olivier, Nocton, Grégory |
| المساهمون: | Laboratoire de chimie moléculaire (LCM), École polytechnique (X)-Institut de Chimie - CNRS Chimie (INC-CNRS)-Centre National de la Recherche Scientifique (CNRS), Institut des Sciences Chimiques de Rennes (ISCR), Université de Rennes (UR)-Institut National des Sciences Appliquées - Rennes (INSA Rennes), Institut National des Sciences Appliquées (INSA)-Institut National des Sciences Appliquées (INSA)-Ecole Nationale Supérieure de Chimie de Rennes (ENSCR)-Institut de Chimie - CNRS Chimie (INC-CNRS)-Centre National de la Recherche Scientifique (CNRS), Institut de Chimie Physique (ICP), Institut de Chimie - CNRS Chimie (INC-CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS), European Research Council (ERC) under the European Union European Research Council (ERC) 716314, ANR (French National Research Agency) French National Research Agency (ANR) ANR-19-CE07-0019-1, CNRS Centre National de la Recherche Scientifique (CNRS)European Commission, Ecole polytechnique, Strategie d'Attractivite Durable SAD18006-LnCPLSMM, European Research Council under the European Union European Research Council (ERC) 725184, ANR-19-CE07-0019,RelaxMax,Complexes organométalliques de lanthanides à relaxation magnétique lente(2019) |
| المصدر: | ISSN: 1433-7851. |
| بيانات النشر: | HAL CCSD Wiley-VCH Verlag |
| سنة النشر: | 2021 |
| المجموعة: | Université de Rennes 1: Publications scientifiques (HAL) |
| مصطلحات موضوعية: | divalent thulium, electron transfer, lanthanides, organometallics, single-molecule magnets, [CHIM]Chemical Sciences |
| الوصف: | International audience ; Divalent lanthanide organometallics are well-known highly reducing compounds usually used for single electron transfer reactivity and small molecule activation. Thus, their very reactive nature prevented for many years the study of their physical properties, such as magnetic studies on a reliable basis. Herein, the access to rare organometallic sandwich compounds of Tm-II with the cyclooctatetraenyl (Cot) ligand impacts on the use of divalent organolanthanide compounds as an additional strategy for the design of performing Single Molecule Magnets (SMM). The first divalent thulium sandwich complex with f(13) configuration behaving as a single-molecule magnet in absence of DC field is highlighted. |
| نوع الوثيقة: | article in journal/newspaper |
| اللغة: | English |
| Relation: | hal-03163652; https://hal.science/hal-03163652; https://hal.science/hal-03163652/document; https://hal.science/hal-03163652/file/Moutet%20et%20al-2021-Bis-cyclooctatetraenyl%20Thulium%28II%29.pdf |
| DOI: | 10.1002/anie.202015428 |
| الاتاحة: | https://hal.science/hal-03163652 https://hal.science/hal-03163652/document https://hal.science/hal-03163652/file/Moutet%20et%20al-2021-Bis-cyclooctatetraenyl%20Thulium%28II%29.pdf https://doi.org/10.1002/anie.202015428 |
| Rights: | info:eu-repo/semantics/OpenAccess |
| رقم الانضمام: | edsbas.ECD11D20 |
| قاعدة البيانات: | BASE |
| DOI: | 10.1002/anie.202015428 |
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