التفاصيل البيبلوغرافية
| العنوان: |
Highly Adaptable Poly(ether-acrylate) Solid Electrolyte for Cathode/Electrolyte Interface Integration and Application in Lithium Metal-Free Solid-State Batteries |
| المؤلفون: |
Quan-yao Liu (8614350), Mao-xiang Jing (4172137), Rui Li (4631), Zhen-hao Huang (11248019), Weiyong Yuan (2365129), Bo-wei Ju (8614356), Xiangqian Shen (730433) |
| سنة النشر: |
2021 |
| المجموعة: |
Smithsonian Institution: Digital Repository |
| مصطلحات موضوعية: |
Biophysics, Biochemistry, Medicine, Biotechnology, Science Policy, Infectious Diseases, Space Science, Biological Sciences not elsewhere classified, Chemical Sciences not elsewhere classified, temperature ion conductivity, si – c, low ion conductivity, linking polymerization method, highly adaptable poly, 8 v ), 5 × 10, poor interface combination, electrolyte integrated structure, showing good practicality, electrolyte interface integration, electrolyte interface combination, free batteries due, solid electrolyte membrane, interface impedance, state batteries, solid electrolyte, free solid, good manufacturability, good adaptability, widely used |
| الوصف: |
Solid polymer electrolyte is expected to be widely used in solid-state lithium batteries due to its good manufacturability and safety. But the low ion conductivity, poor interface combination, and narrow adaptability to different electrodes are hindering the development of solid-state batteries. In this work, a rigid-flexible poly(ether-acrylate) (PEA) solid electrolyte membrane with high room-temperature ion conductivity (1.5 × 10 –4 S/cm), electrochemical stability window (∼4.8 V), and lithium ion migration number (0.81) was prepared using a cross-linking polymerization method. The cathode/electrolyte integrated structure was also created via directly coating electrolyte precursor on the cathode surface to improve the cathode/electrolyte interface combination and decrease the interface impedance, which obviously enhanced the rate performance of the battery. This electrolyte is suitable for LiFePO 4 , LiCoO 2 , NCM622 different-voltage cathodes and lithium metal, Si–C, and graphite anodes, showing good practicality and development prospects in solid-state lithium and lithium metal-free batteries due to its good adaptability. |
| نوع الوثيقة: |
article in journal/newspaper |
| اللغة: |
unknown |
| Relation: |
https://figshare.com/articles/journal_contribution/Highly_Adaptable_Poly_ether-acrylate_Solid_Electrolyte_for_Cathode_Electrolyte_Interface_Integration_and_Application_in_Lithium_Metal-Free_Solid-State_Batteries/16904642 |
| DOI: |
10.1021/acsaem.1c02622.s001 |
| الاتاحة: |
https://doi.org/10.1021/acsaem.1c02622.s001 |
| Rights: |
CC BY-NC 4.0 |
| رقم الانضمام: |
edsbas.E942A979 |
| قاعدة البيانات: |
BASE |