Academic Journal
Extending the Conversion Rate of Sulfur Infiltrated into Microporous Carbon in Carbonate Electrolytes
| العنوان: | Extending the Conversion Rate of Sulfur Infiltrated into Microporous Carbon in Carbonate Electrolytes |
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| المؤلفون: | Para, María L., Calderón, Cecilia A., Drvarič Talian, Sara, Fischer, Florent, Luque, Guillermina L., Barraco, Daniel E., Leiva, Ezequiel P. M., Dominko, Robert |
| المساهمون: | Javna Agencija za Raziskovalno Dejavnost RS |
| المصدر: | Batteries & Supercaps ; volume 5, issue 5 ; ISSN 2566-6223 2566-6223 |
| بيانات النشر: | Wiley |
| سنة النشر: | 2022 |
| المجموعة: | Wiley Online Library (Open Access Articles via Crossref) |
| الوصف: | Infiltration of sulfur into microporous carbon enables the use of carbonate‐based electrolytes due to the formation of a compact cathode electrolyte interface. Passivation of the surface prevents direct contact between electrolyte and sulfur. Consequently, the mechanism of sulfur conversion is changed to a quasi‐solid‐state mechanism with a single sloping plateau related to sulfur conversion in the narrow pores. The narrow size of pores determines the overall pore volume of the microporous carbon and with that sulfur maximum ratio within carbon‐sulfur composite. Additionally, a confinement of sulfur in the narrow pores has an impact on sulfur conversion into Li 2 S 2 /Li 2 S due to volumetric changes when sulfur is reduced. In this work, we show that the degree of the conversion of sulfur into end discharge products can be extended by lowering the cutoff potential during the discharge process. A higher degree of conversion process causes cracks in the carbon structure enabling a significant increase of capacity while a compact and flexible passivation layer prevents contact with the electrolyte. Quasi solid‐state reduction of sulfur is kinetically more favored compared to the consequent oxidation process. Electrochemical impedance spectroscopy measurements show diffusional restrictions in the lower part of the discharge curve that can be correlated with hindered transport due to volumetric changes caused by the reduction of sulfur into Li 2 S 2 /Li 2 S. |
| نوع الوثيقة: | article in journal/newspaper |
| اللغة: | English |
| DOI: | 10.1002/batt.202100374 |
| الاتاحة: | http://dx.doi.org/10.1002/batt.202100374 https://onlinelibrary.wiley.com/doi/pdf/10.1002/batt.202100374 https://onlinelibrary.wiley.com/doi/full-xml/10.1002/batt.202100374 |
| Rights: | http://creativecommons.org/licenses/by/4.0/ |
| رقم الانضمام: | edsbas.E91DEF5 |
| قاعدة البيانات: | BASE |
| DOI: | 10.1002/batt.202100374 |
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