Academic Journal
Performance Improvements of Bixin and Metal-Bixin Complexes Sensitized Solar Cells by 1-Methyl-3-propylimidazolium Iodide in Electrolyte System
| العنوان: | Performance Improvements of Bixin and Metal-Bixin Complexes Sensitized Solar Cells by 1-Methyl-3-propylimidazolium Iodide in Electrolyte System |
|---|---|
| المؤلفون: | Rahmalia, Winda, Septiani, Septiani, Naselia, Uray, Amira, Usman, Thamrin, Silalahi, Imelda, Hotmarisi, Mouloungui, Zéphirin |
| المساهمون: | Tanjungpura University, Partenaires INRAE, Laboratoire de Chimie Agro-Industrielle (LCA), Ecole nationale supérieure des ingénieurs en arts chimiques et technologiques (ENSIACET), Institut National Polytechnique (Toulouse) (Toulouse INP), Université de Toulouse (UT)-Université de Toulouse (UT)-Institut National Polytechnique (Toulouse) (Toulouse INP), Université de Toulouse (UT)-Université de Toulouse (UT)-Ecole d'Ingénieurs de Purpan (INP - PURPAN), Université de Toulouse (UT)-Université de Toulouse (UT)-Institut National de Recherche pour l’Agriculture, l’Alimentation et l’Environnement (INRAE), Ministry of Research Technology and the Higher Education Republic of Indonesia (KEMENRISTEK DIKTI) through the National Competitive Research (217/SP2H/LT/DRPM/2019). |
| المصدر: | ISSN: 1411-9420. |
| بيانات النشر: | CCSD |
| سنة النشر: | 2021 |
| المجموعة: | Université Toulouse III - Paul Sabatier: HAL-UPS |
| مصطلحات موضوعية: | bixin, complex, dye-sensitized solar cells (DSSCs), 1-methyl-3propylimidazolium iodide (MPII), [SDV]Life Sciences [q-bio] |
| الوصف: | International audience ; Bixin is one of the potential natural sensitizers used in dye-sensitized solar cells (DSSCs). In this study, bixin was complexed with Cu(II) and Zn(II) to increase its stability. The formation of the complexes was indicated by shifting peaks absorption and the changes in the fine spectral structure observed from the UV-Vis absorption spectra. The metal-bixin complex occurs due to the interaction between the ester groups of bixin and the metal. Bixin, Cu-bixin, and Zn-bixin were used separately as sensitizers in DSSCs. The DSSCs performance was then improved by adding 1-methyl-3-propylimidazolium iodide (MPII) to the electrolyte system. The presence of MPII 0.4 M in KI-I2 electrolyte produced a higher ionic conductivity value (20.44 mS cm-1) than that without MPII (11.14 mS cm-1). This electrolyte system significantly improved DSSCs performance. Under a light intensity of 300 W/m 2 , the maximum energy conversion efficiencies of DSSC with bixin, Cu-bixin, and Zn-bixin as sensitizers are 0.084, 0.081, and 0.005%, respectively. The Zn-bixin-based DSSC was stable under high light intensity. Under 700 W/m 2 , its maximum energy conversion efficiency reaches 0.125%. There was a synergistic work observed between the metal-bixin complex and the MPII based electrolyte. This result can open the way for constructing functional materials for solar cell applications. |
| نوع الوثيقة: | article in journal/newspaper |
| اللغة: | English |
| Relation: | WOS: 000659892000014 |
| DOI: | 10.22146/ijc.60633 |
| الاتاحة: | https://hal.inrae.fr/hal-03301366 https://hal.inrae.fr/hal-03301366v1/document https://hal.inrae.fr/hal-03301366v1/file/60633-209103-3-PB.pdf https://doi.org/10.22146/ijc.60633 |
| Rights: | http://creativecommons.org/licenses/by-nc-nd/ ; info:eu-repo/semantics/OpenAccess |
| رقم الانضمام: | edsbas.E819FB28 |
| قاعدة البيانات: | BASE |
| DOI: | 10.22146/ijc.60633 |
|---|