Academic Journal

Mechanism of Cd(II) and Cu(II) Adsorption onto Few-Layered Magnetic Graphene Oxide as an Efficient Adsorbent

التفاصيل البيبلوغرافية
العنوان: Mechanism of Cd(II) and Cu(II) Adsorption onto Few-Layered Magnetic Graphene Oxide as an Efficient Adsorbent
المؤلفون: Ting Guo (210829), Chaoke Bulin (4601695), Zeyu Ma (689881), Bo Li (112195), Yanghuan Zhang (10981797), Bangwen Zhang (4601692), Ruiguang Xing (4601698), Xin Ge (167893)
سنة النشر: 2021
المجموعة: Smithsonian Institution: Digital Repository
مصطلحات موضوعية: Biophysics, Biochemistry, Molecular Biology, Physiology, Ecology, Hematology, Environmental Sciences not elsewhere classified, Biological Sciences not elsewhere classified, Chemical Sciences not elsewhere classified, Physical Sciences not elsewhere classified, pair electrons, Fe 3 O 4, FLMGO, pseudo-second-order model, adsorption quantities, graphene oxide, metal remediation, components graphene oxide, Efficient Adsorbent Heavy metal con., chemical interaction, adsorption efficiency, 7 min, interaction mechanism, Cu
الوصف: Heavy metal contamination caused by industrial discharge is a challenging environmental issue. Herein, an efficient adsorbent based on few-layered magnetic graphene oxide (FLMGO) was fabricated, characterized, and utilized to remove aqueous Cd­(II) and Cu­(II). Results present that the two components graphene oxide (GO) and Fe 3 O 4 of FLMGO promote mutually, enabling FLMGO to outperform either GO or Fe 3 O 4 . Specifically, FLMGO adsorbs Cd­(II) and Cu­(II) with adsorption quantities of 401.14 and 1114.22 mg·g –1 in 5 and 7 min, respectively. Moreover, FLMGO can be readily recovered via magnetic separation using a hand-held magnet. Adsorptions are spontaneous, endothermic, and entropy increasing, which are the best described by the Freundlich and pseudo-second-order model. The interaction mechanism is as follows: lone pair electrons in CO- and C–O-related groups were coordinated toward Cd­(II) and Cu­(II) to induce chemical interaction. The high adsorption efficiency endows FLMGO with encouraging application potential in heavy metal remediation.
نوع الوثيقة: article in journal/newspaper
اللغة: unknown
Relation: https://figshare.com/articles/journal_contribution/Mechanism_of_Cd_II_and_Cu_II_Adsorption_onto_Few-Layered_Magnetic_Graphene_Oxide_as_an_Efficient_Adsorbent/14794161
DOI: 10.1021/acsomega.1c01770.s001
الاتاحة: https://doi.org/10.1021/acsomega.1c01770.s001
Rights: CC BY-NC 4.0
رقم الانضمام: edsbas.E7B79EEC
قاعدة البيانات: BASE
الوصف
DOI:10.1021/acsomega.1c01770.s001