Academic Journal
3D Porous Metal–Organic Skeleton Based on Polyoxometalate Nanoclusters as an Anode in a Lithium-Ion Battery
| العنوان: | 3D Porous Metal–Organic Skeleton Based on Polyoxometalate Nanoclusters as an Anode in a Lithium-Ion Battery |
|---|---|
| المؤلفون: | Shuang Sun, Liping Cui, Kai Yu, Meilin Wang, Jinghua Lv, Shuanghong Ge, Baibin Zhou |
| سنة النشر: | 2023 |
| مصطلحات موضوعية: | Biochemistry, Pharmacology, Biotechnology, Ecology, Developmental Biology, Mental Health, Infectious Diseases, Astronomical and Space Sciences not elsewhere classified, Biological Sciences not elsewhere classified, Chemical Sciences not elsewhere classified, superior redox ability, polyporous hybrid material, layer structure composed, intersecting tunnels based, construct porous materials, 6 , 5 , 4 , 2 , 18 , cl }{ h, btb )[{ ag, ion battery basket, ion battery, unique double, pz chains, polyoxometalate nanoclusters, like poms, like polyoxometalate, ligand strategy |
| الوصف: | Basket-like polyoxometalate (POM) nanoclusters possess bulky space barriers and limited coordination active sites; therefore, it is difficult for them to bond with functional metal–organic building units to construct porous materials. To overcome this bottleneck, we adopt a dual-ligand strategy to anchor basket-like POM nanoclusters onto a Ag-pz metal–organic chain yielding a polyporous hybrid material, (H 4 btb)[{Ag 4 (H 2 O)(pz) 5 Cl}{H 2 SrP 6 Mo 18 O 73 }]·4H 2 O ( BAS-MOF-1 ). It is the first three-dimensional (3D) net with intersecting tunnels based on a unique double-layer structure composed of {P 6 Mo 18 O 73 } nodes and Ag-pz chains. As an anode for a Li-ion battery (LIB), this material shows higher lithiation capacity, stability, and rate than zero-dimensional (0D) control compounds, which can be ascribed to the superior redox ability of basket-like POMs and stable organic–inorganic porous structures. |
| نوع الوثيقة: | article in journal/newspaper |
| اللغة: | unknown |
| Relation: | https://figshare.com/articles/journal_contribution/3D_Porous_Metal_Organic_Skeleton_Based_on_Polyoxometalate_Nanoclusters_as_an_Anode_in_a_Lithium-Ion_Battery/24915137 |
| DOI: | 10.1021/acsanm.3c05315.s001 |
| الاتاحة: | https://doi.org/10.1021/acsanm.3c05315.s001 https://figshare.com/articles/journal_contribution/3D_Porous_Metal_Organic_Skeleton_Based_on_Polyoxometalate_Nanoclusters_as_an_Anode_in_a_Lithium-Ion_Battery/24915137 |
| Rights: | CC BY-NC 4.0 |
| رقم الانضمام: | edsbas.E5B0A1E9 |
| قاعدة البيانات: | BASE |
| DOI: | 10.1021/acsanm.3c05315.s001 |
|---|