Academic Journal
Remendable polymers via reversible Diels–Alder cycloaddition of anthracene‐containing copolymers with fullerenes
| العنوان: | Remendable polymers via reversible Diels–Alder cycloaddition of anthracene‐containing copolymers with fullerenes |
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| المؤلفون: | Kötteritzsch, Julia, Geitner, Robert, Ahner, Johannes, Abend, Marcus, Zechel, Stefan, Vitz, Jürgen, Hoeppener, Stephanie, Dietzek, Benjamin, Schmitt, Michael, Popp, Jürgen, Schubert, Ulrich S., Hager, Martin D. |
| المساهمون: | Deutsche Forschungsgemeinschaft |
| المصدر: | Journal of Applied Polymer Science ; volume 135, issue 10 ; ISSN 0021-8995 1097-4628 |
| بيانات النشر: | Wiley |
| سنة النشر: | 2017 |
| المجموعة: | Wiley Online Library (Open Access Articles via Crossref) |
| الوصف: | Poly(lauryl methacrylate)s with anthracene moieties in the side chain were converted with C 60 ‐fullerene and phenyl‐C 61 ‐butyric acid methyl ester (PCBM), resulting in new remendable (self‐healing) polymeric materials. The utilization of differently substituted anthracene monomers enabled the tuning of the reactivity and the resulting mechanical properties. Copolymers with different contents of the anthracene moieties were synthesized and characterized using size exclusion chromatography, 1 H nuclear magnetic resonance (NMR) spectroscopy as well as differential scanning calorimetry (DSC). 1 H NMR spectroscopic studies were utilized in order to investigate the reversibility of the Diels–Alder reaction between copolymers with C 60 ‐fullerene and PCBM, respectively, in solution. In order to investigate the conversion of the polymers with C 60 ‐fullerene and PCBM in bulk, additionally, DSC, nanoindentation, rheology, atomic force microscopy (AFM), 3D microscopy, simultaneous thermal analysis (STA) and FT‐Raman investigations were performed. The fullerene‐containing copolymers could be healed in a temperature range of 40–80 °C. Consequently, a new generation of low temperature remendable polymers could be established. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018 , 135 , 45916. |
| نوع الوثيقة: | article in journal/newspaper |
| اللغة: | English |
| DOI: | 10.1002/app.45916 |
| الاتاحة: | http://dx.doi.org/10.1002/app.45916 https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fapp.45916 https://onlinelibrary.wiley.com/doi/pdf/10.1002/app.45916 |
| Rights: | http://onlinelibrary.wiley.com/termsAndConditions#vor |
| رقم الانضمام: | edsbas.E4C8477E |
| قاعدة البيانات: | BASE |
| DOI: | 10.1002/app.45916 |
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