Academic Journal
Morphological evolution of two-dimensional porous hexagonal trimesic acid framework
العنوان: | Morphological evolution of two-dimensional porous hexagonal trimesic acid framework |
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المؤلفون: | Tothadi, S, Koner, K, Dey, K, Addicoat, M, Banerjee, R |
بيانات النشر: | American Chemical Society (ACS) |
سنة النشر: | 2020 |
المجموعة: | Nottingham Trent University's Institutional Repository (IRep) |
الوصف: | Hexagonal single crystal structure (Form II) of trimesic acid (TMA) has been isolated by dissolving the interpenetrated Form I of TMA in tetrahydrofuran. Form II (hexagonal) was converted to Form I (interpenetrated) at room temperature through some intermediate structures. A detailed time-dependent FESEM study shows that the external morphology of Form II (hexagonal) is a hollow hexagonal tube that mimics its crystal structure. The block-shaped (morphology) of Form I (interpenetrated) was converted to the hollow hexagonal tube through some intermediate morphologies which are corresponding to particular crystal structures. Here, we have established a strong correlation between crystal structures with the morphology. These hollow tubes have been employed for Rhodamine B dye adsorption studies and showed an uptake of 82%, much more significant than Form I (interpenetrated) (39%) due to the presence of a pore channel in the crystal structure. |
نوع الوثيقة: | article in journal/newspaper |
وصف الملف: | text |
اللغة: | English |
Relation: | http://irep.ntu.ac.uk/id/eprint/43522/1/1333609_Addicoat.pdf; TOTHADI, S., KONER, K., DEY, K., ADDICOAT, M. and BANERJEE, R., 2020. Morphological evolution of two-dimensional porous hexagonal trimesic acid framework. ACS Applied Materials and Interfaces, 12 (13), pp. 15588-15594. ISSN 1944-8244 |
DOI: | 10.1021/acsami.0c01398 |
الاتاحة: | http://irep.ntu.ac.uk/id/eprint/43522/ http://irep.ntu.ac.uk/id/eprint/43522/1/1333609_Addicoat.pdf https://doi.org/10.1021/acsami.0c01398 |
رقم الانضمام: | edsbas.E4718EA8 |
قاعدة البيانات: | BASE |
DOI: | 10.1021/acsami.0c01398 |
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