Academic Journal
Structural determination of oleanane-28,13b-olide and taraxerane-28,14b-olide fluorolactonization products from the reaction of oleanolic acid with SelectfluorTM
| العنوان: | Structural determination of oleanane-28,13b-olide and taraxerane-28,14b-olide fluorolactonization products from the reaction of oleanolic acid with SelectfluorTM |
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| المؤلفون: | A. Eadsforth, Megan, Kong, Linghan, Whitehead, George F. S., Vitorica-Yrezabal, Iñigo Javier, T. O’Keefe, Raymond, A. Bryce, Richard, C. Whitehead, Roger |
| بيانات النشر: | International Union of Crystallography |
| سنة النشر: | 2024 |
| المجموعة: | DIGIBUG: Repositorio Institucional de la Universidad de Granada |
| مصطلحات موضوعية: | crystal structure, oleanolic acid, fluorolactone |
| الوصف: | The X-ray crystal structure data of 12-α-fluoro-3β-hydroxyolean-28,13β-olide methanol hemisolvate, 2C30H47FO3·CH3OH, (1), and 12-α-fluoro-3β-hydroxytaraxer-28,14β-olide methanol hemisolvate, 2C30H47FO3·CH3OH, (2), are described. The fluorolactonization of oleanolic acid using SelectfluorTM yielded a mixture of the six-membered δ-lactone (1) and the unusual seven-membered γ-lactone (2) following a 1,2-shift of methyl C-27 from C-14 to C-13. ; Biotechnology and Biological Sciences Research Council (studentship No. 2110646 to Megan A Eadsforth; grant No. BB/S00047X/1 |
| نوع الوثيقة: | article in journal/newspaper |
| اللغة: | English |
| Relation: | A. Eadsforth, M. et. al. Acta Cryst. (2024). E80, 857–862. [https://doi.org/10.1107/S2056989024006480]; https://hdl.handle.net/10481/96624 |
| DOI: | 10.1107/S2056989024006480 |
| الاتاحة: | https://hdl.handle.net/10481/96624 https://doi.org/10.1107/S2056989024006480 |
| Rights: | Atribución 4.0 Internacional ; http://creativecommons.org/licenses/by/4.0/ ; open access |
| رقم الانضمام: | edsbas.E46E20A0 |
| قاعدة البيانات: | BASE |
| DOI: | 10.1107/S2056989024006480 |
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