التفاصيل البيبلوغرافية
| العنوان: |
IZM-2: A promising new zeolite for the selective hydroisomerization of long-chain n-alkanes |
| المؤلفون: |
Antoine Fécant, Christophe Bouchy, Emmanuelle Guillon, Johan A. Martens, Nicolas Bats, Filipe Marques Mota |
| سنة النشر: |
2013 |
| مصطلحات موضوعية: |
H800 - Chemical, process & energy engineering, H810 - Chemical engineering, IZM-2, m-Xylene isomerization, n-Decane test, n-Hexadecane, Pore architecture, Selective hydroisomerization, Zeolite |
| الوصف: |
IZM-2 (IFPEn Zeolitic Material number 2) is an aluminosilicate zeolite with unknown structure. The synthesis is performed using 1,6-bis(methylpiperidinium)hexyl dibromide template. According to SEM and TEM, IZM-2 particles consist of intergrowths of 20–60 nm nanocrystals of various orientations. The nitrogen adsorption isotherm is characteristic of a nanosize microporous material. Characterization of the pore architecture using m-xylene isomerization and disproportionation and n-decane isomerization-hydrocracking test reaction suggests the presence of two types of pores of different diameter. The catalytic fingerprints of 10-membered ring pores are observed and concluded to be present next to wider pores, tentatively qualified as 12-membered ring pores. Pt/IZM-2 was evaluated in the hydroisomerization of n-hexadecane. Pt/IZM-2 is an excellent hydroisomerization catalyst especially suited for formation of multi-branched skeletal isomers. IZM-2 is a valuable addition to the family of 10-membered ring zeolites and may find application in hydroisomerization processes for selective hydroisomerization of long-chain n-alkanes. |
| نوع الوثيقة: |
article in journal/newspaper |
| اللغة: |
unknown |
| Relation: |
10779/lincoln.24875112.v1; https://figshare.com/articles/journal_contribution/IZM-2_A_promising_new_zeolite_for_the_selective_hydroisomerization_of_long-chain_n-alkanes/24875112 |
| الاتاحة: |
https://figshare.com/articles/journal_contribution/IZM-2_A_promising_new_zeolite_for_the_selective_hydroisomerization_of_long-chain_n-alkanes/24875112 |
| Rights: |
CC BY 4.0 |
| رقم الانضمام: |
edsbas.E3F011E1 |
| قاعدة البيانات: |
BASE |