Electrochemical Determination of L-Glutamate on a Carbon-Containing Electrode Modified with Gold by Voltammetry

التفاصيل البيبلوغرافية
العنوان: Electrochemical Determination of L-Glutamate on a Carbon-Containing Electrode Modified with Gold by Voltammetry
المؤلفون: Dorozhko, Elena Vladimirovna, Korotkova, Elena Ivanovna, Shabaeva, Aliya Anvarovna, Mosolkov, Aleksey Yurievich
بيانات النشر: Elsevier
سنة النشر: 2015
المجموعة: Tomsk Polytechnic University (TPU): Electronic Archive / Томский политехнический университет: Электронный архив TPU
مصطلحات موضوعية: глутамат, вольтамперометрия, углеродсодержащие электроды, усилители, вкус, ароматы
الوصف: In this paper the L-glutamate electrochemical behavior on a carbon-containing electrode modified with gold in simulated solutions by cyclic voltammetry have been studied. The analytical signal of glutamate reduction at the potential of -0.8 V in pH 9.19 has been found. It has been determined that the cathodic reduction of glutamate is irreversible and mainly controlled by diffusion in the reduction electrode process of glutamate. The conditions for glutamate determination in simulated solutions by voltammetry have been found. The plots of current versus concentration present a linear behavior from 3.2·10{-4} to 2.5·10{-3} M. The detection limit is 4.4 10{-5} M. The glutamate determination in simulated solutions has resulted in acceptable deviation from the stated concentration where relative errors are -2.7 to +2.6%.
نوع الوثيقة: conference object
اللغة: English
Relation: Procedia Chemistry. Vol. 15 : Chemistry and Chemical Engineering in XXI century (CCE 2015). — Amsterdam, 2015.; Electrochemical Determination of L-Glutamate on a Carbon-Containing Electrode Modified with Gold by Voltammetry / E. V. Dorozhko [et al.] // Procedia Chemistry. — 2015. — Vol. 15 : Chemistry and Chemical Engineering in XXI century (CCE 2015) : XVI International Scientific Conference dedicated to Professor L.P. Kulyov, 25-29 May 2015, Tomsk, Russia. — [P. 365-370].; http://earchive.tpu.ru/handle/11683/15079
DOI: 10.1016/j.proche.2015.10.058
الاتاحة: http://earchive.tpu.ru/handle/11683/15079
https://doi.org/10.1016/j.proche.2015.10.058
Rights: info:eu-repo/semantics/openAccess
رقم الانضمام: edsbas.DD8FF279
قاعدة البيانات: BASE
الوصف
DOI:10.1016/j.proche.2015.10.058