Academic Journal
On the Unimolecular Reactions of CH3O and CH2OH
| العنوان: | On the Unimolecular Reactions of CH3O and CH2OH |
|---|---|
| المؤلفون: | Adams, George F, Bartlett, Rodney J, Purvis, George D |
| المساهمون: | FLORIDA UNIV GAINESVILLE QUANTUM THEORY PROJECT |
| المصدر: | DTIC AND NTIS |
| سنة النشر: | 1981 |
| المجموعة: | Defense Technical Information Center: DTIC Technical Reports database |
| مصطلحات موضوعية: | Organic Chemistry, Nuclear Physics & Elementary Particle Physics, ISOMERIZATION, MOLECULAR PROPERTIES, REACTION KINETICS, COMPUTATIONS, DECOMPOSITION, DISSOCIATION, HYDROGEN, METHYL RADICALS, REPRINTS, UNIMOLECULAR REACTIONS, METHOXY, HIGH ENERGY BARRIERS |
| الوصف: | Recent experiments suggest that the isomerization reaction CH3O reversible reaction CH2OH may compete with the hydrogen dissociation reaction CH3O yields CH2O + H. We report correlated many-body calculations of barrier heights for these reactions and other decompositions of CH3O and CH2OH. The barriers for isomerization and dissociation are similar, while the reaction CH3O yields CHO + H2 has a higher energy barrier. ; Published in Chemical Physics Letters, v87 n4 p311-314, 2 Apr 1982. |
| نوع الوثيقة: | text |
| وصف الملف: | text/html |
| اللغة: | English |
| Relation: | http://www.dtic.mil/docs/citations/ADA121275 |
| الاتاحة: | http://www.dtic.mil/docs/citations/ADA121275 http://oai.dtic.mil/oai/oai?&verb=getRecord&metadataPrefix=html&identifier=ADA121275 |
| Rights: | Approved for public release; distribution is unlimited. |
| رقم الانضمام: | edsbas.DD22E2D5 |
| قاعدة البيانات: | BASE |
| الوصف غير متاح. |