Academic Journal
The structures of 1-(2-halo-6-fluorophenylmethyl)-1-methylimidazolium bromide salts
| العنوان: | The structures of 1-(2-halo-6-fluorophenylmethyl)-1-methylimidazolium bromide salts |
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| المؤلفون: | Lorenzini, Fabio, Marr, Andrew C., Saunders, Graham C., Thomas, Hayden |
| المصدر: | Lorenzini , F , Marr , A C , Saunders , G C & Thomas , H 2018 , ' The structures of 1-(2-halo-6-fluorophenylmethyl)-1-methylimidazolium bromide salts ' , Journal of Fluorine Chemistry . https://doi.org/10.1016/j.jfluchem.2018.03.006 |
| سنة النشر: | 2018 |
| المجموعة: | Queen's University Belfast: Research Portal |
| الوصف: | The crystal structures of 1-(2-halo-6-fluorophenylmethyl)-1-methylimidazolium bromide salts and 1-(2-trifluoromethyl-6-fluorophenylmethyl)-1-methylimidazolium bromide [MeNC3H3NCH2C6H3X-2-F-6]+.Br- [X = F (1), Cl (2), Br (3), I (4), CF3 (5)] have been determined. The crystal structure of the hydrate of salt 1 contains π–π stacked imidazolium···difluorophenyl···difluorophenyl···imidazolium units. Those of salts 2, 4 and 5 possess bromide···halofluorophenyl···halofluorophenyl···bromide motifs comprising anion–π and π–π stacking interactions. That of salt 4 also contains bromide···iodide halogen bonding. The crystal structure of the sesquihydrate of salt 3 possesses bromine···halofluorophenyl···halofluorophenyl···bromine motifs. |
| نوع الوثيقة: | article in journal/newspaper |
| وصف الملف: | application/pdf |
| اللغة: | English |
| DOI: | 10.1016/j.jfluchem.2018.03.006 |
| الاتاحة: | https://pure.qub.ac.uk/en/publications/9317f852-37a5-4a7c-a97d-b5166b82a4c0 https://doi.org/10.1016/j.jfluchem.2018.03.006 https://pureadmin.qub.ac.uk/ws/files/147968210/2018_JFLUORCHEM_Saunders_2018.pdf |
| Rights: | info:eu-repo/semantics/openAccess |
| رقم الانضمام: | edsbas.DB397668 |
| قاعدة البيانات: | BASE |
| DOI: | 10.1016/j.jfluchem.2018.03.006 |
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