Coexisting Z-type charge and bond order in metallic NaRu2O4

التفاصيل البيبلوغرافية
العنوان:	Coexisting Z-type charge and bond order in metallic NaRu2O4
المؤلفون:	Yogi, Arvind Kumar, Yaresko, Alexander, Sathish, C. I., Sim, Hasung, Morikawa, Daisuke, Nuss, Juergen, Tsuda, Kenji, Noda, Yukio., Khomskii, Daniel I., Park, Je-Geun
المساهمون:	National Research Foundation of Korea
المصدر:	Communications Materials ; volume 3, issue 1 ; ISSN 2662-4443
بيانات النشر:	Springer Science and Business Media LLC
سنة النشر:	2022
الوصف:	How particular bonds form in quantum materials has been a long-standing puzzle. Two key concepts dealing with charge degrees of freedom are dimerization (forming metal-metal bonds) and charge ordering. Since the 1930s, these two concepts have been frequently invoked to explain numerous exciting quantum materials, typically insulators. Here we report dimerization and charge ordering within the dimers coexisting in metallic NaRu 2 O 4 . By combining high-resolution x-ray diffraction studies and theoretical calculations, we demonstrate that this unique phenomenon occurs through a new type of bonding, which we call Z-type ordering. The low-temperature superstructure has strong dimerization in legs of zigzag ladders, with short dimers in legs connected by short zigzag bonds, forming Z-shape clusters: simultaneously, site-centered charge ordering also appears. Our results demonstrate the yet unknown flexibility of quantum materials with the intricate interplay among orbital, charge, and lattice degrees of freedom.
نوع الوثيقة:	article in journal/newspaper
اللغة:	English
DOI:	10.1038/s43246-022-00224-8
الاتاحة:	http://dx.doi.org/10.1038/s43246-022-00224-8 https://www.nature.com/articles/s43246-022-00224-8.pdf https://www.nature.com/articles/s43246-022-00224-8
Rights:	https://creativecommons.org/licenses/by/4.0 ; https://creativecommons.org/licenses/by/4.0
رقم الانضمام:	edsbas.D94E212E
قاعدة البيانات:	BASE

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الوصف
DOI:	10.1038/s43246-022-00224-8