التفاصيل البيبلوغرافية
| العنوان: |
2,2′-Biaryldicarboxylate Synthesis via Electrocatalytic Dehydrogenative C–H/C–H Coupling of Benzoic Acids |
| المؤلفون: |
Zhongyi Zeng (1795999), Jonas F. Goebel (10840728), Xianming Liu (1602160), Lukas J. Gooßen (1777882) |
| سنة النشر: |
2021 |
| المجموعة: |
Smithsonian Institution: Digital Repository |
| مصطلحات موضوعية: |
Biophysics, Biochemistry, Medicine, Microbiology, Neuroscience, Evolutionary Biology, Immunology, Mental Health, Space Science, Environmental Sciences not elsewhere classified, Chemical Sciences not elsewhere classified, Physical Sciences not elsewhere classified, benzoic acids, oxidative carboxylate-directed ortho, compound, coupling, Biaryldicarboxylate, naphthyl -1-carboxylic acids |
| الوصف: |
2,2′-Biaryldicarboxylates are important functionalities in bioactive compounds, functional materials, and chiral catalysts. These compounds have been found to be conveniently accessible from benzoic acids via Rh-catalyzed electrooxidative C–H/C–H couplings, giving valuable dihydrogen as the byproduct. In an undivided cell with Pt electrodes, RhCl 3 ·3H 2 O catalyzes the oxidative carboxylate-directed ortho -homocoupling of various aromatic acids with a current efficiency of 67%. The protocol is operationally simple, tolerates a wide variety of functional groups, and does not require the exclusion of air and moisture. Heterodimerizations via cross-dehydrogenative couplings of naphthyl-1-carboxylic acids with acrylic or benzoic acids were also shown to work. |
| نوع الوثيقة: |
article in journal/newspaper |
| اللغة: |
unknown |
| Relation: |
https://figshare.com/articles/journal_contribution/2_2_-Biaryldicarboxylate_Synthesis_via_Electrocatalytic_Dehydrogenative_C_H_C_H_Coupling_of_Benzoic_Acids/14637213 |
| DOI: |
10.1021/acscatal.1c01127.s001 |
| الاتاحة: |
https://doi.org/10.1021/acscatal.1c01127.s001 |
| Rights: |
CC BY-NC 4.0 |
| رقم الانضمام: |
edsbas.D7E7B3B4 |
| قاعدة البيانات: |
BASE |